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- W2061699650 abstract "Raman scattering enhancement was observed in systems where different metal oxide semiconductors (TiO 2 , Fe 2 O 3 , ZrO 2 and CeO 2 ) were modified with enediol ligands. The intensity of Raman scattering was dependent on laser frequency andcorrelated with the extinction coefficient of the charge-transfer complex of the enediol ligands and nanoparticles. Theintensity and frequency of the Raman bands was found to depend on the chemical composition of the enediol ligand andthe chemical composition (and crystallinity) of the nanoparticles. The intensity of the Raman signal depends on thenumber of surface binding sites, electron density of the ligands and their dipole moment. We also found that Ramanscattering is observed for the bioconjugated system, where a peptide is linked to the surface of the particle through acatechol linker. These studies are important since these bioconjugates can be used to form the basis of Raman-based, invitro and importantly in vivo biodetection, cell labeling and imaging, and nanotherapeutic strategies." @default.
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- W2061699650 date "2010-08-19" @default.
- W2061699650 modified "2023-09-24" @default.
- W2061699650 title "Mechanistic studies into the Raman enhancement of enediol-semiconducting nanoparticle conjugates and their use in biological applications" @default.
- W2061699650 doi "https://doi.org/10.1117/12.862931" @default.
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