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- W2061707047 abstract "Abstract A novel hydroxyl‐terminated short‐chain penta‐armed phosphazene was prepared. This penta‐armed compound was studied as an initiator for the synthesis of asymmetric penta‐armed poly(ε‐caprolactone)s in the presence of stannous octoate. The effect of molar ratio of monomer to initiator was investigated. Thermal analysis revealed that the penta‐armed poly(ε‐caprolactone)s possessed lower melting point and crystallinity than linear ones. The penta‐armed poly(ε‐caprolactone)s with long chain‐length exhibited higher onset decomposition temperature and maximum decomposition temperature than linear ones owing to the presence of the phosphazene core. The in vitro degradation of linear and penta‐armed PCL was performed in phosphate buffer solution at 37 and 55 °C. Copyright © 2005 Society of Chemical Industry" @default.
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- W2061707047 date "2005-05-03" @default.
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- W2061707047 title "Asymmetric penta-armed poly(ɛ-caprolactone)s with short-chain phosphazene core: synthesis, characterization, andin vitro degradation" @default.
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- W2061707047 doi "https://doi.org/10.1002/pi.1840" @default.
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