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- W2061742017 abstract "In order to obtain structure—biological activity data the synthesis of 15 new terpenoid lactones from germacranolides, eudesmanolides, guaianolides and elemanolides was undertaken. These and 15 other compounds were then tested as plant growth regulators. These studies established that the biological activity associated with the α-methylene-γ-lactone moiety in a terpenoid lactone is further enhanced when a cyclopropane ring is placed in the α,β-position to the lactone carbonyl. No exception to this structure—activity data has been noted so far. Significantly, this activity is increased when a trisubstituted (Z)-double bond is in the position of conjugation and the only exception to this is (Z)-C13-methyl dehydrosaussurea lactone which is only as active as water. Almost always a C-4 epoxy, or a C-4, C-10 ether group in the guaianolide systems further enhances the biological activity associated with the parent lactone. A similar effect of the epoxy group is not observed in the case of eudesmanolides." @default.
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- W2061742017 date "1983-01-01" @default.
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- W2061742017 title "Structure and plant growth activity relationship in terpenoid lactones" @default.
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