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- W2061774472 abstract "The crystal structures of 3,4;3',4'-bis(ethylenedithio)-2,2',5,5'-tetrathiafulvalenium hexafluorophosphate chloroacetyl chloride solvate, (1), C 10 H 8 S 8 1/2+ .1/2PF 6 - 1/2C 2 H 2 Cl 2 O, 3,4;3',4'-bis(ethylenedithio)-2,2',5,5'-tetrathiafulvalenium hexafluorophosphate tetrahydrofuran solvate, (2), C 10 H 8 Si 8 + .PF 6 - .1/2C 4 H 8 O, and 3,4;3',4'-bis-(ethylenedithio)-2,2',5,5'-tetrathiafulvalenium perchlorate, (3), C 10 H 8 S 8 + .ClO 4 - , have been determined. Compounds (1) and (2) crystallize in the P1 space group. The structure of (1) consists of layers of BEDT-TTF ions separated by planes of PF 6 - ions and chloroacetyl chloride molecules. The BEDT-TTF ions are stacked in a face-to-face manner with short S...S contacts linking these stacks. Compound (2) consists of layers of BEDT-TTF face-to-face dimers with PF 6 - ions and tetrahydrofuran (THF) molecules filling cavities separating these layers. As in compound (1), there are short S...S contacts between dimers resulting from the side-by-side mode of packing. Compound (3) crystallizes in the C2/m space group and consists of layers of BEDT-TTF ions, stacked in a staggered side-by-side manner with one type of S...S contact, separated by layers of perchlorate ions." @default.
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- W2061774472 date "1995-11-15" @default.
- W2061774472 modified "2023-09-27" @default.
- W2061774472 title "Three BEDT-TTF Salts" @default.
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- W2061774472 doi "https://doi.org/10.1107/s0108270195005592" @default.
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