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- W2061781147 abstract "Novel N2B heterocycles (1–5) are formed from the reaction of ethylenediamine derivatives with 2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzaldehyde (2-HC(O)C6H4Bpin; pin = 1,2-O2C2Me4). X-ray diffraction studies have been carried out on four examples and show that reactions are selective in giving the isomer where the least substituted amine coordinates to the Lewis-acidic boron atom. Reaction of 2-HC(O)C6H4Bpin with diethylenetriamine gave a heterocycle (6) with a pendant primary amine group, which reacts further with 2-pyridinecarboxaldehyde to give a potential ligand (7) for transition metals. All new compounds show considerable antifungal activity against Aspergillus niger and Aspergillus flavus and moderate antibacterial activity against Bacillus cereus." @default.
- W2061781147 created "2016-06-24" @default.
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- W2061781147 date "2003-01-01" @default.
- W2061781147 modified "2023-10-16" @default.
- W2061781147 title "Synthesis and antifungal and antibacterial bioactivity of cyclic diamines containing boronate esters" @default.
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- W2061781147 doi "https://doi.org/10.1039/b304500e" @default.
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