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- W2061782021 abstract "[3-(Ethylthio)allyl]titanium reagent generated easily from allyl ethyl sulfides condensed with aldehydes to give erythro-β-hydroxy sulfides in highly regio- and stereoselective manner. In contrast, crotyl ethyl sulfide reacted with aldehydes affording δ-hydroxy vinyl sulfide exclusively. The substitution pattern of the starting sulfide can have a pronounced effect on the selectivity in this condensation reaction. erythro-β-Hydroxy sulfide obtained was transformed stereoselectively to the trans-vinyloxirane or 1,3-alkadiene." @default.
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- W2061782021 date "1984-10-01" @default.
- W2061782021 modified "2023-10-17" @default.
- W2061782021 title "Selective Condensation of [3-(Alkylthio)allyl]titanium Reagent with Carbonyl Compounds" @default.
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