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• W2061806313 abstract "Solid state 13C CP/MAS studies of poly(vinyl chloride) (PVC)−bis(2-ethylhexyl) phthalate (DOP) have been carried out to elucidate the dynamics of polymer−plasticizer interaction at the molecular level. 13C NMR spectra, spin−lattice relaxation time T1(C) and spin−spin relaxation time T2(C) were obtained for various PVC−DOP samples. Line widths of 〉CHCl show a sharp increase due to the strong hydrogen-bonding interaction between the 〉CO (ester) group of DOP and 〉CHCl of PVC with various concentrations of DOP. The spin−lattice relaxation time T1(C) also confirms the presence of a strong interaction due to hydrogen bonding. The less mobile intermediate phase is mostly affected by the presence of plasticizer. The spin−spin relaxation time T2(C) shows that DOP is a mixed type plasticizer showing the features of both molecular and structural type plasticization." @default.
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• W2061806313 date "1996-01-01" @default.
• W2061806313 modified "2023-10-18" @default.
• W2061806313 title "Study of Polymer−Plasticizer Interaction by ¹³C CP/MAS NMR Spectroscopy: Poly(vinyl chloride)−Bis(2-ethylhexyl) Phthalate System" @default.
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• W2061806313 doi "https://doi.org/10.1021/ma951086x" @default.
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