FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2061821378> ?p ?o ?g. }

• W2061821378 endingPage "174307" @default.
• W2061821378 startingPage "174307" @default.
• W2061821378 abstract "Close-coupling calculations and experiment are combined in this work, which is aimed at establishing a set of state-to-state rate coefficients for elementary processes ij → lm in O(2):O(2) collisions at low temperature involving the rotational states i, j, l, m of the vibrational ground state of (16)O(2)((3)Σ(g)(-)). First, a set of cross sections for inelastic collisions is calculated as a function of the collision energy at the converged close-coupled level via the MOLSCAT code, using a recent ab-initio potential energy surface for O(2)-O(2) [M. Bartolomei et al., J. Chem. Phys. 133, 124311 (2010)]. Then, the corresponding rates for the temperature range 4 ≤ T ≤ 34 K are derived from the cross sections. The link between theory and experiment is a Master Equation which accounts for the time evolution of rotational populations in a reference volume of gas in terms of the collision rates. This Master Equation provides a linear function of the rates for each rotational state and temperature. In the experiment, the evolution of rotational populations is measured by Raman spectroscopy in a tiny reference volume (≈2 × 10(-4) mm(3)) of O(2) travelling along the axis of a supersonic jet at a velocity of ≈700 m/s. The accuracy of the calculated rates is assessed experimentally for 10 ≤ T ≤ 34 K by means of the Master Equation. The rates, jointly with their confidence interval estimated by Monte Carlo simulation, account to within the experimental uncertainty for the evolution of the populations of the N = 1, 3, 5, 7 rotational triads along the supersonic jet. Confidence intervals range from ≈6% for the dominant rates at 34 K, up to ≈17% at 10 K. These results provide an experimental validation of state-to-state rates for O(2):O(2) inelastic collisions calculated in the close-coupling approach and, indirectly, of the anisotropy of the O(2)-O(2) intermolecular potential employed in the calculation for energies up to 300 cm(-1)." @default.
• W2061821378 created "2016-06-24" @default.
• W2061821378 creator A5003474105 @default.
• W2061821378 creator A5029567800 @default.
• W2061821378 creator A5036196321 @default.
• W2061821378 creator A5039295731 @default.
• W2061821378 creator A5088981928 @default.
• W2061821378 date "2011-05-07" @default.
• W2061821378 modified "2023-09-26" @default.
• W2061821378 title "Inelastic collisions in molecular oxygen at low temperature (4 ⩽<i>T</i>⩽ 34 K). Close-coupling calculations versus experiment" @default.
• W2061821378 cites W1484740070 @default.
• W2061821378 cites W1555735976 @default.
• W2061821378 cites W1570138018 @default.
• W2061821378 cites W1619312465 @default.
• W2061821378 cites W1666671404 @default.
• W2061821378 cites W1963744362 @default.
• W2061821378 cites W1964553900 @default.
• W2061821378 cites W1969621452 @default.
• W2061821378 cites W1971836215 @default.
• W2061821378 cites W1980716313 @default.
• W2061821378 cites W1982237064 @default.
• W2061821378 cites W1982302487 @default.
• W2061821378 cites W1984121179 @default.
• W2061821378 cites W1984268956 @default.
• W2061821378 cites W1984747334 @default.
• W2061821378 cites W1987925333 @default.
• W2061821378 cites W1996255038 @default.
• W2061821378 cites W1997242928 @default.
• W2061821378 cites W1998521347 @default.
• W2061821378 cites W2002854348 @default.
• W2061821378 cites W2005808692 @default.
• W2061821378 cites W2008071367 @default.
• W2061821378 cites W2012096412 @default.
• W2061821378 cites W2013456622 @default.
• W2061821378 cites W2014464846 @default.
• W2061821378 cites W2021990403 @default.
• W2061821378 cites W2026133892 @default.
• W2061821378 cites W2026682897 @default.
• W2061821378 cites W2026813075 @default.
• W2061821378 cites W2026938716 @default.
• W2061821378 cites W2029154001 @default.
• W2061821378 cites W2032339998 @default.
• W2061821378 cites W2033400356 @default.
• W2061821378 cites W2042898547 @default.
• W2061821378 cites W2048664324 @default.
• W2061821378 cites W2048865362 @default.
• W2061821378 cites W2049302231 @default.
• W2061821378 cites W2051595235 @default.
• W2061821378 cites W2052058045 @default.
• W2061821378 cites W2067959220 @default.
• W2061821378 cites W2070116034 @default.
• W2061821378 cites W2072642830 @default.
• W2061821378 cites W2075048001 @default.
• W2061821378 cites W2080533687 @default.
• W2061821378 cites W2082020280 @default.
• W2061821378 cites W2084685560 @default.
• W2061821378 cites W2086143839 @default.
• W2061821378 cites W2087483218 @default.
• W2061821378 cites W2090772593 @default.
• W2061821378 cites W2092414642 @default.
• W2061821378 cites W2095537508 @default.
• W2061821378 cites W2104569602 @default.
• W2061821378 cites W2108379386 @default.
• W2061821378 cites W2129373842 @default.
• W2061821378 cites W2139657668 @default.
• W2061821378 cites W2231012206 @default.
• W2061821378 cites W3101426318 @default.
• W2061821378 doi "https://doi.org/10.1063/1.3585978" @default.
• W2061821378 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/21548687" @default.
• W2061821378 hasPublicationYear "2011" @default.
• W2061821378 type Work @default.
• W2061821378 sameAs 2061821378 @default.
• W2061821378 citedByCount "16" @default.
• W2061821378 countsByYear W20618213782012 @default.
• W2061821378 countsByYear W20618213782013 @default.
• W2061821378 countsByYear W20618213782014 @default.
• W2061821378 countsByYear W20618213782015 @default.
• W2061821378 countsByYear W20618213782017 @default.
• W2061821378 countsByYear W20618213782019 @default.
• W2061821378 countsByYear W20618213782020 @default.
• W2061821378 countsByYear W20618213782021 @default.
• W2061821378 countsByYear W20618213782022 @default.
• W2061821378 countsByYear W20618213782023 @default.
• W2061821378 crossrefType "journal-article" @default.
• W2061821378 hasAuthorship W2061821378A5003474105 @default.
• W2061821378 hasAuthorship W2061821378A5029567800 @default.
• W2061821378 hasAuthorship W2061821378A5036196321 @default.
• W2061821378 hasAuthorship W2061821378A5039295731 @default.
• W2061821378 hasAuthorship W2061821378A5088981928 @default.
• W2061821378 hasBestOaLocation W20618213782 @default.
• W2061821378 hasConcept C105795698 @default.
• W2061821378 hasConcept C121332964 @default.
• W2061821378 hasConcept C125277925 @default.
• W2061821378 hasConcept C128805008 @default.
• W2061821378 hasConcept C131584629 @default.
• W2061821378 hasConcept C147120987 @default.
• W2061821378 hasConcept C184779094 @default.
• W2061821378 hasConcept C185592680 @default.

• next