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• W2061827075 abstract "The reaction of FeCl3 · 6H2O, potassium hydrotris(pyrazolyl)borate (KTp) and KSCN gives [FeTp2][TpFe(NCS)3] (1) and [FeTp2]3[Fe(NCS)6] (2), respectively. The bond lengths and angles indicate that both complexes have [FeTp2]+ cations where Fe(III) ions are in typical low-spin state, and in counter ions, [TpFe(NCS)3]− for 1 and [Fe(NCS)6]3− for 2 are both in high-spin state. Variable temperature magnetic susceptibility and ESR results also show that there are double spin states of iron(III) ions within the crystal lattice of both compounds." @default.
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• W2061827075 date "2005-01-01" @default.
• W2061827075 modified "2023-09-22" @default.
• W2061827075 title "Synthesis, crystal structures and properties of iron(III) complexes exhibited both high-spin and low-spin states within the crystal lattice" @default.
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• W2061827075 doi "https://doi.org/10.1016/j.ica.2004.07.051" @default.
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