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- W2061830414 abstract "A nonhydrolytic low-temperature route to ternary V−Ti−Si catalysts has been developed. The vanadium overlayer is deposited first, by the complete reaction of VOX3 (X is Cl or OiPr) with the surface hydroxyl groups of pyrogenic silica. Ti(OiPr)4 migrates underneath the vanadium overlayer to give a heterobinuclear complex containing one Ti and one V, bound to the silica surface by an Si−O−Ti link. The heterobinuclear complex is not formed when TiCl4 is used, nor can it be generated by first depositing Ti(OR)4." @default.
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- W2061830414 date "1998-01-13" @default.
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- W2061830414 title "Nonhydrolytic Surface Synthesis of a Heterobimetallic V−Ti Alkoxide Complex on Silica" @default.
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- W2061830414 doi "https://doi.org/10.1021/cm9706199" @default.
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