FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2061872904> ?p ?o ?g. }

• W2061872904 endingPage "1649" @default.
• W2061872904 startingPage "1640" @default.
• W2061872904 abstract "The solvation parameter model is used to characterize the separation properties of four open-tubular columns for gas chromatography at low and intermediate column temperatures covering the range 60-240 degrees C. Solute descriptors for compounds suitable for characterizing columns over the intermediate temperature range are optimized using an iterative procedure. These compounds, and those previously recommended for the lower temperature range, are used to provide system constant maps for Rxi-5Sil MS, Rxi-17, Rtx-TNT and Rtx-TNT2 columns suitable for merging with a system constants database with entries for more than 50 columns. The Rxi-5Sil MS column is shown to have separation properties similar to the silphenylene-dimethylsiloxane copolymer stationary phase (DB-5ms) but these two columns are not selectivity equivalent. The Rxi-17 column has similar separation properties to the Rxi-50 column but is not selectivity equivalent to it. Rxi-17 is a poly(dimethyldiphenylsiloxane) stationary phase containing 50% diphenylsiloxane monomer and Rxi-50 a poly(methylphenylsiloxane) stationary phase with the same nominal composition but a different monomer structure. The difference in monomer structure results in only small changes in selectivity, and for all but the most demanding separations, the columns are interchangeable. The application-specific column (energetic materials) Rtx-TNT is shown to be selectivity equivalent to columns coated with the poly(dimethyldiphenylsiloxane) stationary phases containing 5% diphenylsiloxane monomer. The Rtx-TNT2 column is selectivity equivalent to the proprietary Rtx-OPPesticides column. Rtx-OPPesticides is a low bleed stationary phase, possibly based on silarylene-siloxane chemistry, with a composition designed to mimic the separation properties of the poly(dimethylmethyltrifluoropropylsiloxane) stationary phases containing 35% methyltrifluoropropylsiloxane monomer. Selectivity equivalence of columns is determined by the statistical agreement in system constants at 20 degrees C intervals over the full temperature range from 60 to 240 degrees C, and by the construction of correlation plots for the retention factors of varied compounds for the same temperature intervals." @default.
• W2061872904 created "2016-06-24" @default.
• W2061872904 creator A5040129806 @default.
• W2061872904 creator A5042984744 @default.
• W2061872904 creator A5046828929 @default.
• W2061872904 creator A5048185249 @default.
• W2061872904 creator A5074846649 @default.
• W2061872904 date "2009-03-01" @default.
• W2061872904 modified "2023-10-18" @default.
• W2061872904 title "Extension of the system constants database for open-tubular columns: System maps at low and intermediate temperatures for four new columns" @default.
• W2061872904 cites W1975105894 @default.
• W2061872904 cites W1981280721 @default.
• W2061872904 cites W1987748440 @default.
• W2061872904 cites W1988415099 @default.
• W2061872904 cites W2004372324 @default.
• W2061872904 cites W2005020926 @default.
• W2061872904 cites W2010861831 @default.
• W2061872904 cites W2012898602 @default.
• W2061872904 cites W2013676016 @default.
• W2061872904 cites W2026612577 @default.
• W2061872904 cites W2027624715 @default.
• W2061872904 cites W2049659614 @default.
• W2061872904 cites W2057647807 @default.
• W2061872904 cites W2062005644 @default.
• W2061872904 cites W2077802053 @default.
• W2061872904 cites W2142750296 @default.
• W2061872904 doi "https://doi.org/10.1016/j.chroma.2008.11.057" @default.
• W2061872904 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/19081101" @default.
• W2061872904 hasPublicationYear "2009" @default.
• W2061872904 type Work @default.
• W2061872904 sameAs 2061872904 @default.
• W2061872904 citedByCount "35" @default.
• W2061872904 countsByYear W20618729042012 @default.
• W2061872904 countsByYear W20618729042013 @default.
• W2061872904 countsByYear W20618729042014 @default.
• W2061872904 countsByYear W20618729042015 @default.
• W2061872904 countsByYear W20618729042017 @default.
• W2061872904 countsByYear W20618729042018 @default.
• W2061872904 countsByYear W20618729042019 @default.
• W2061872904 countsByYear W20618729042020 @default.
• W2061872904 countsByYear W20618729042021 @default.
• W2061872904 countsByYear W20618729042022 @default.
• W2061872904 crossrefType "journal-article" @default.
• W2061872904 hasAuthorship W2061872904A5040129806 @default.
• W2061872904 hasAuthorship W2061872904A5042984744 @default.
• W2061872904 hasAuthorship W2061872904A5046828929 @default.
• W2061872904 hasAuthorship W2061872904A5048185249 @default.
• W2061872904 hasAuthorship W2061872904A5074846649 @default.
• W2061872904 hasConcept C113196181 @default.
• W2061872904 hasConcept C118792377 @default.
• W2061872904 hasConcept C13355873 @default.
• W2061872904 hasConcept C148093993 @default.
• W2061872904 hasConcept C15920480 @default.
• W2061872904 hasConcept C161790260 @default.
• W2061872904 hasConcept C166940927 @default.
• W2061872904 hasConcept C178790620 @default.
• W2061872904 hasConcept C185592680 @default.
• W2061872904 hasConcept C2524010 @default.
• W2061872904 hasConcept C2776139660 @default.
• W2061872904 hasConcept C2780551164 @default.
• W2061872904 hasConcept C32909587 @default.
• W2061872904 hasConcept C33923547 @default.
• W2061872904 hasConcept C43617362 @default.
• W2061872904 hasConcept C44280652 @default.
• W2061872904 hasConcept C51724486 @default.
• W2061872904 hasConcept C521977710 @default.
• W2061872904 hasConceptScore W2061872904C113196181 @default.
• W2061872904 hasConceptScore W2061872904C118792377 @default.
• W2061872904 hasConceptScore W2061872904C13355873 @default.
• W2061872904 hasConceptScore W2061872904C148093993 @default.
• W2061872904 hasConceptScore W2061872904C15920480 @default.
• W2061872904 hasConceptScore W2061872904C161790260 @default.
• W2061872904 hasConceptScore W2061872904C166940927 @default.
• W2061872904 hasConceptScore W2061872904C178790620 @default.
• W2061872904 hasConceptScore W2061872904C185592680 @default.
• W2061872904 hasConceptScore W2061872904C2524010 @default.
• W2061872904 hasConceptScore W2061872904C2776139660 @default.
• W2061872904 hasConceptScore W2061872904C2780551164 @default.
• W2061872904 hasConceptScore W2061872904C32909587 @default.
• W2061872904 hasConceptScore W2061872904C33923547 @default.
• W2061872904 hasConceptScore W2061872904C43617362 @default.
• W2061872904 hasConceptScore W2061872904C44280652 @default.
• W2061872904 hasConceptScore W2061872904C51724486 @default.
• W2061872904 hasConceptScore W2061872904C521977710 @default.
• W2061872904 hasIssue "10" @default.
• W2061872904 hasLocation W20618729041 @default.
• W2061872904 hasLocation W20618729042 @default.
• W2061872904 hasOpenAccess W2061872904 @default.
• W2061872904 hasPrimaryLocation W20618729041 @default.
• W2061872904 hasRelatedWork W1973491893 @default.
• W2061872904 hasRelatedWork W1984761979 @default.
• W2061872904 hasRelatedWork W1989548074 @default.
• W2061872904 hasRelatedWork W2017461668 @default.
• W2061872904 hasRelatedWork W2023640914 @default.
• W2061872904 hasRelatedWork W2055009077 @default.
• W2061872904 hasRelatedWork W2125030406 @default.
• W2061872904 hasRelatedWork W2385781661 @default.
• W2061872904 hasRelatedWork W2792214021 @default.

• next