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- W2061877065 abstract "Lithium mobility in LiM2(PO4)3 compounds, M = Ge and Sn, has been investigated by 7Li Nuclear Magnetic Resonance (NMR) spectroscopy, and deduced information compared with that reported previously in Ti, Zr and Hf members of the series in the temperature range 100–500 K. From the analysis of 7Li NMR quadrupole interactions (CQ and η parameters), spin–spin T2−1 and spin–lattice T1−1 relaxation rates, structural sites occupancy and mobility of lithium have been deduced. Below 250 K, Li ions are preferentially located at M1 sites in rhombohedral phases, but occupy intermediate M12 sites between M1 and M2 sites in triclinic ones. In high-temperature rhombohedral phases, a superionic state is achieved when residence times at M1 and M12 sites become similar and correlation effects on Li motion decrease. This state can be obtained by large order–disorder transformations in rhombohedral phases or by sharp first order transitions in triclinic ones. The presence of two relaxation mechanisms in T1−1 plots of rhombohedral phases has been associated with departures of conductivity from the Arrhenius behavior. Long term mobility of lithium is discussed in terms of the cation vacancy distribution along conduction paths." @default.
- W2061877065 created "2016-06-24" @default.
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- W2061877065 date "2011-01-01" @default.
- W2061877065 modified "2023-10-14" @default.
- W2061877065 title "Li mobility in Nasicon-type materials LiM2(PO4)3, M = Ge, Ti, Sn, Zr and Hf, followed by 7Li NMR spectroscopy" @default.
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- W2061877065 doi "https://doi.org/10.1039/c1dt10516g" @default.
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