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- W2061928252 abstract "Abstract Electronic absorption spectra of aqueous solutions of Na, K, Ba, Ag and Pb azides, perchlorates and nitrates have been measured. For a particular series it has been found that these spectra are unique and the observed absorption has been attributed to excitations from the highest occupied molecular orbital to the lowest unoccupied molecular orbital. Spectra of single crystals of all these salts have also been measured. It is found that those salts which absorb on the long wavelength side of the anionic absorption are the heavy metal salts, specifically the elements not having closed shell configurations. In each of these three series it is these same salts which are the most unstable, e.g. Pb(N3)2 is much more unstable than NaN3. There is therefore a direct correlation between the absorption spectra of these materials and their sensitivity." @default.
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- W2061928252 date "1967-11-01" @default.
- W2061928252 modified "2023-10-01" @default.
- W2061928252 title "Electronic absorption spectra of metallic azides, perchlorates and nitrates and their related explosive properties" @default.
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- W2061928252 doi "https://doi.org/10.1016/0584-8539(67)80178-8" @default.
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