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• W2061943584 abstract "Abstract Research presented in this paper investigates the electronic properties and surface reactivity of FeAl(110) and polycrystalline TiAl and NiAl toward carbon monoxide. X-ray photoelectron spectroscopy (XPS) and ultraviolet photoelectron spectroscopy (UPS) have been used to characterize the electronic structure of the clean and CO-exposed surfaces. Temperature programmed desorption (TPD) shows CO desorption states below 470 K on all the aluminide surfaces. UPS shows that CO adsorption is molecular on FeAl(110) and NiAl at 130 and 200 K, respectively. The majority of CO is found to be dissociated on TiAl at 200 K. Adsorption of CO on FeAl(110) at 315 K results in both molecular and dissociated species, as determined by XPS. Heating this CO/FeAl(110) system results in further dissociation and CO desorption near 430 K. XPS data suggests that surface oxygen, resulting from CO dissociation, preferentially binds to the aluminum component." @default.
• W2061943584 created "2016-06-24" @default.
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• W2061943584 date "1993-10-01" @default.
• W2061943584 modified "2023-09-23" @default.
• W2061943584 title "A photoelectron spectroscopy and thermal desorption study of CO on FeAl(110) and polycrystalline TiAl and NiAl" @default.
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• W2061943584 doi "https://doi.org/10.1016/0039-6028(93)90277-q" @default.
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