FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2061947079> ?p ?o ?g. }

• W2061947079 endingPage "6241" @default.
• W2061947079 startingPage "6232" @default.
• W2061947079 abstract "New platinum(IV)-coordinated carbohydrate complexes [PtMe3L]BF4 (14E−21E, 22D−24D) have been prepared from the reaction of [PtMe3(Me2CO)3]BF4 (1) with a wide range of isopropylidene-protected carbohydrates L‘ in acetone. These complexation reactions can be accompanied by a platinum-promoted cleavage of an isopropylidene group (14E, L‘ = 1,2;5,6-di-O-isopropylidene-α-d-glucofuranose (1A), L = 1,2-O-isopropylidene-α-d-glucofuranose; 15E, L‘ = 3-O-acetyl-1,2;5,6-di-O-isopropylidene-α-d-glucofuranose (2A), L = 3-O-acetyl-1,2-O-isopropylidene-α-d-glucofuranose; 16E, L‘ = 3-O-(methylsulfonyl)-1,2;5,6-di-O-isopropylidene-α-d-glucofuranose (3A), L = 3-O-(methylsulfonyl)-1,2-O-isopropylidene-α-d-glucofuranose; 17E, L‘ = 1,2;5,6-di-O-isopropylidene-α-d-allofuranose (4A), L = 1,2-O-isopropylidene-α-d-allofuranose; 18E, L‘ = 2,3;4,6-di-O-isopropylidene-2-keto-l-gulonic acid (5A), L = 2,3-O-isopropylidene-2-keto-l-gulonic acid; 19E, L‘ = 2,3;4,6-di-O-isopropylidene-α-l-sorbofuranose (6A), L = 2,3-O-isopropylidene-α-l-sorbofuranose). In some cases, complexation proceeds without the loss of an isopropylidene group (14E, L = L‘ = 1,2-O-isopropylidene-α-d-glucofuranose (10B); 15E, L = L‘ = 3-O-acetyl-1,2-O-isopropylidene-α-d-glucofuranose (11B); 20E, L = L‘ = 1,2-O-isopropylidene-α-d-xylofuranose (12B), 21E, L = L‘ = 5,6-O-isopropylidene-d-gulono-γ-lactone (13B)). Furthermore, complexes 22D−24D with diprotected carbohydrate ligands undergo a platinum-promoted cleavage of an isopropylidene group in wet methylene chloride to give 19E, cleavage of the carbohydrate ligand L (7A) to give [PtMe3(H2O)3]BF4, and substitution of the isopropylidene ligand by an aqua ligand to give [PtMe3L(H2O)]BF4 (24D‘, L = 2,3;4,5-di-O-isopropylidene-β-d-fructopyranose), respectively. Complex 14E reacted in acetone within 1 week in a platinum-promoted addition of an isopropylidene protecting group, yielding [PtMe3L‘]BF4 (25D, L‘ = 1,2;5,6-di-O-isopropylidene-α-d-glucofuranose). The results show that carbohydrates can act as tridentate neutral ligands with a wide variety of donor sites: 3 × OH (14E, 17E−19E), 2 × OH + OCOMe (15E), 2 × OH + OSO2Me (16E), 2 × OH + Oring (20E), 2 × OH + Oacetal (21E), 1 × OH + Oring + Oacetal (22D - 25D). Bidentate ligation (OH + Oring) is observed in 24D‘. Complexes 14E singly 13C-labeled at each of the saccharide carbons were prepared, and an analysis of the J couplings involving the labeled carbons permitted an assignment of the solution conformation of the carbohydrate ligand. X-ray structure analysis of 19E (monoclinic, P21, a = 8.607(3) Å, b = 9.955(4) Å, c = 11.415(4) Å, Z = 2) and 24D‘ (orthorhombic, P212121, a = 9.851(2) Å, b = 11.141(4) Å, c = 20.418(6) Å, Z = 4) exhibits the same coordination in the solid state as in solution, namely, via the three hydroxyl groups, yielding a strained-cyclic system (19E) and a five-membered 1,3,2-dioxaplatina ring (24D‘)." @default.
• W2061947079 created "2016-06-24" @default.
• W2061947079 creator A5006835259 @default.
• W2061947079 creator A5007712618 @default.
• W2061947079 creator A5017089825 @default.
• W2061947079 creator A5028688085 @default.
• W2061947079 creator A5068514871 @default.
• W2061947079 date "1999-06-17" @default.
• W2061947079 modified "2023-10-10" @default.
• W2061947079 title "Novel Platinum(IV)−Carbohydrate Complexes: Metal Ion Coordination Behavior of Monosaccharides in Organic Solvents" @default.
• W2061947079 cites W190293211 @default.
• W2061947079 cites W1976610285 @default.
• W2061947079 cites W2000228498 @default.
• W2061947079 cites W2030094834 @default.
• W2061947079 cites W2045832896 @default.
• W2061947079 cites W2058246461 @default.
• W2061947079 cites W2058350969 @default.
• W2061947079 cites W2061314753 @default.
• W2061947079 cites W2067658764 @default.
• W2061947079 cites W2073585386 @default.
• W2061947079 cites W2090349663 @default.
• W2061947079 cites W2121282265 @default.
• W2061947079 cites W2129088196 @default.
• W2061947079 cites W2149724725 @default.
• W2061947079 cites W2155653333 @default.
• W2061947079 cites W2165494881 @default.
• W2061947079 cites W2319442207 @default.
• W2061947079 cites W239834479 @default.
• W2061947079 cites W2952812782 @default.
• W2061947079 cites W4244337434 @default.
• W2061947079 cites W55890731 @default.
• W2061947079 doi "https://doi.org/10.1021/ja9902726" @default.
• W2061947079 hasPublicationYear "1999" @default.
• W2061947079 type Work @default.
• W2061947079 sameAs 2061947079 @default.
• W2061947079 citedByCount "45" @default.
• W2061947079 countsByYear W20619470792012 @default.
• W2061947079 countsByYear W20619470792015 @default.
• W2061947079 countsByYear W20619470792016 @default.
• W2061947079 crossrefType "journal-article" @default.
• W2061947079 hasAuthorship W2061947079A5006835259 @default.
• W2061947079 hasAuthorship W2061947079A5007712618 @default.
• W2061947079 hasAuthorship W2061947079A5017089825 @default.
• W2061947079 hasAuthorship W2061947079A5028688085 @default.
• W2061947079 hasAuthorship W2061947079A5068514871 @default.
• W2061947079 hasConcept C118859902 @default.
• W2061947079 hasConcept C155647269 @default.
• W2061947079 hasConcept C161790260 @default.
• W2061947079 hasConcept C178790620 @default.
• W2061947079 hasConcept C185592680 @default.
• W2061947079 hasConcept C2778977261 @default.
• W2061947079 hasConcept C2781213060 @default.
• W2061947079 hasConcept C2781251403 @default.
• W2061947079 hasConcept C518104683 @default.
• W2061947079 hasConcept C544153396 @default.
• W2061947079 hasConcept C71240020 @default.
• W2061947079 hasConceptScore W2061947079C118859902 @default.
• W2061947079 hasConceptScore W2061947079C155647269 @default.
• W2061947079 hasConceptScore W2061947079C161790260 @default.
• W2061947079 hasConceptScore W2061947079C178790620 @default.
• W2061947079 hasConceptScore W2061947079C185592680 @default.
• W2061947079 hasConceptScore W2061947079C2778977261 @default.
• W2061947079 hasConceptScore W2061947079C2781213060 @default.
• W2061947079 hasConceptScore W2061947079C2781251403 @default.
• W2061947079 hasConceptScore W2061947079C518104683 @default.
• W2061947079 hasConceptScore W2061947079C544153396 @default.
• W2061947079 hasConceptScore W2061947079C71240020 @default.
• W2061947079 hasIssue "26" @default.
• W2061947079 hasLocation W20619470791 @default.
• W2061947079 hasOpenAccess W2061947079 @default.
• W2061947079 hasPrimaryLocation W20619470791 @default.
• W2061947079 hasRelatedWork W1493536597 @default.
• W2061947079 hasRelatedWork W1974690120 @default.
• W2061947079 hasRelatedWork W2124402821 @default.
• W2061947079 hasRelatedWork W2388580798 @default.
• W2061947079 hasRelatedWork W2391786769 @default.
• W2061947079 hasRelatedWork W2905377268 @default.
• W2061947079 hasRelatedWork W2967139480 @default.
• W2061947079 hasRelatedWork W3121510936 @default.
• W2061947079 hasRelatedWork W613125200 @default.
• W2061947079 hasRelatedWork W2066394148 @default.
• W2061947079 hasVolume "121" @default.
• W2061947079 isParatext "false" @default.
• W2061947079 isRetracted "false" @default.
• W2061947079 magId "2061947079" @default.
• W2061947079 workType "article" @default.