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- W2061950004 abstract "113Cd NMR is examined as a tool for the study of ion-polyelectrolyte interactions. Binding of Cd2+ to polystyrenesulfonate gives chemical shift changes of up to 35 ppm, thus demonstrating that the method is very sensitive. Information on the Cd2+ exchange rate, on the fraction of bound ions, and on the competition of the ion with Ca2+ and Mg2+ (partly from 25Mg NMR) is obtained. The applicability of the method is compared with that of the quadrupole relaxation method. Both electrostatic theories and site-binding models have been used to describe the interaction between Cd2+ and polyanion. Only the site-binding model agrees with the experimental results." @default.
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- W2061950004 date "1981-10-01" @default.
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- W2061950004 title "113Cd NMR study of cadmium ion interaction with polyelectrolytes" @default.
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- W2061950004 doi "https://doi.org/10.1016/0022-2364(81)90107-4" @default.
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