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- W2061957336 abstract "Das Natriumsalz des 3-Phenylacetylacetons (1) reagiert mit Carbonsäurechloriden zu den Enolestern 2–4. Am Beispiel des Benzoesäureenolesters 4Z und Trifluoressigsäure wird gezeigt, daß zwischen der Freien Aktivierungsenthalpie ΔG für die 1,5-Acylgruppenwanderung und dem Logarithmus der relativen Säurekonzentration eine lineare Abhängigkeit besteht. Acyl Group Migration, VI: Acid Catalysis During Acyl Group Migration in O-Acylated 1,3-Diketones The sodium salt of 3-phenylacetylacetone (1) reacts with carbonyl chlorides to form the enol esters 2–4. The observed 1,5-acyl group migration of the Z-isomers, e. g. 4Z, Shows acid catalysis. A linear relationship has been found between the free activation enthalpie ΔG and the logarithm of the relative acid concentration of trifluoroacetic acid." @default.
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- W2061957336 date "1976-04-01" @default.
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- W2061957336 title "Acylgruppenwanderung, VI: Säurekatalyse bei der AcylgruppenwanderungO-acylierter 1,3-Diketone" @default.
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- W2061957336 doi "https://doi.org/10.1002/cber.19761090416" @default.
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