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- W2061962283 abstract "Abstract The chemisorption and subsequent reaction of bromine on Cr(110 has been studied by Auger spectroscopy, LEED, Δφ, and thermal desorption measurements. For gas doses of 18 molecules m −2 , very efficient dissociative chemisorption leads to a series of well-ordered, out-of-registry compression structures. Uniquely, however, the overlayer falls back into registry at saturation coverage; at this point the appearance of glide symmetry indicates that the three-fold coordinated adsorption sites are occupied exclusively. Bromine → metal charge transfer occurs during adsorption (in contrast to Cr(100)). On raising the temperature at low coverages, the surface phase decomposes by evaporation as CrBr molecules; at higher coverages the desorption product switches to CrBr 2 . Continuous growth of bulk CrBr 2 sets in at high gas exposures, this corrosion reaction proceeding at a rate which is ten times slower than the rate of overlayer formation. The chromium dibromide layer also evaporates as CrBr 2 (g). Structural relationships with related metal-halogen systems are discussed." @default.
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- W2061962283 date "1984-03-01" @default.
- W2061962283 modified "2023-09-24" @default.
- W2061962283 title "Structural and reactive properties at the metal-halogen interface: The interaction of bromine with chromium (110)" @default.
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- W2061962283 doi "https://doi.org/10.1016/0039-6028(84)90510-7" @default.
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