Matches in SemOpenAlex for { <https://semopenalex.org/work/W2061975283> ?p ?o ?g. }
- W2061975283 abstract "Two isomers, (1) and (1a), of [NiL2(NCS)2](L =N-methylpropane-1,3-diamine) have been synthesised. Isomer (1) undergoes an irreversible endothermic solid-state phase transition (383–413 K, ΔH= 8.1 kJ mol–1) transforming into species (1a). This isomerisation also takes place on crystallisation from methanol, ethanol, chloroform, or acetonitrile. Species (1a) has been characterised by X-ray crystallography. The crystals are monoclinic, space group P21/c with four formula units in a unit cell of dimensions a= 8.136(2), b= 13.057(2), c= 15.235(3)A, and β= 90.75(1)°. The structure has been solved by Patterson and successive Fourier syntheses and refined by block-diagonal least-squares calculations to R= 0.048 and R′= 0.061 for 2 311 reflections. The metal atom co-ordination is nearly octahedral with the two thiocyanate groups in cis position. The overall configuration and conformation of the complex molecule is Λpp(two chairs fold in the same rotational direction). Isomer (1) probably exists in the Λpa form (two chairs fold apart from each other)." @default.
- W2061975283 created "2016-06-24" @default.
- W2061975283 creator A5017963965 @default.
- W2061975283 creator A5029788328 @default.
- W2061975283 creator A5038626459 @default.
- W2061975283 creator A5059066482 @default.
- W2061975283 creator A5084652325 @default.
- W2061975283 date "1990-01-01" @default.
- W2061975283 modified "2023-09-25" @default.
- W2061975283 title "Synthesis of conformational isomers, thermally induced isomerism, and crystal structure of cis-di-isothiocyanatobis(N-methylpropane-1,3-diamine)nickel(II)" @default.
- W2061975283 cites W1965991437 @default.
- W2061975283 cites W1987584631 @default.
- W2061975283 cites W2040691405 @default.
- W2061975283 cites W2083222512 @default.
- W2061975283 cites W2084728074 @default.
- W2061975283 cites W2085229131 @default.
- W2061975283 cites W2087651449 @default.
- W2061975283 cites W2326749411 @default.
- W2061975283 cites W2466065374 @default.
- W2061975283 cites W2952002943 @default.
- W2061975283 cites W2954359141 @default.
- W2061975283 cites W1994432178 @default.
- W2061975283 doi "https://doi.org/10.1039/dt9900002347" @default.
- W2061975283 hasPublicationYear "1990" @default.
- W2061975283 type Work @default.
- W2061975283 sameAs 2061975283 @default.
- W2061975283 citedByCount "13" @default.
- W2061975283 countsByYear W20619752832015 @default.
- W2061975283 countsByYear W20619752832017 @default.
- W2061975283 crossrefType "journal-article" @default.
- W2061975283 hasAuthorship W2061975283A5017963965 @default.
- W2061975283 hasAuthorship W2061975283A5029788328 @default.
- W2061975283 hasAuthorship W2061975283A5038626459 @default.
- W2061975283 hasAuthorship W2061975283A5059066482 @default.
- W2061975283 hasAuthorship W2061975283A5084652325 @default.
- W2061975283 hasConcept C115624301 @default.
- W2061975283 hasConcept C126661725 @default.
- W2061975283 hasConcept C161790260 @default.
- W2061975283 hasConcept C176788430 @default.
- W2061975283 hasConcept C178790620 @default.
- W2061975283 hasConcept C179104552 @default.
- W2061975283 hasConcept C185592680 @default.
- W2061975283 hasConcept C18705241 @default.
- W2061975283 hasConcept C188027245 @default.
- W2061975283 hasConcept C198819137 @default.
- W2061975283 hasConcept C2776294642 @default.
- W2061975283 hasConcept C2777463227 @default.
- W2061975283 hasConcept C2780871995 @default.
- W2061975283 hasConcept C2781144210 @default.
- W2061975283 hasConcept C32909587 @default.
- W2061975283 hasConcept C43617362 @default.
- W2061975283 hasConcept C504270822 @default.
- W2061975283 hasConcept C55493867 @default.
- W2061975283 hasConcept C61276311 @default.
- W2061975283 hasConcept C71240020 @default.
- W2061975283 hasConcept C8010536 @default.
- W2061975283 hasConceptScore W2061975283C115624301 @default.
- W2061975283 hasConceptScore W2061975283C126661725 @default.
- W2061975283 hasConceptScore W2061975283C161790260 @default.
- W2061975283 hasConceptScore W2061975283C176788430 @default.
- W2061975283 hasConceptScore W2061975283C178790620 @default.
- W2061975283 hasConceptScore W2061975283C179104552 @default.
- W2061975283 hasConceptScore W2061975283C185592680 @default.
- W2061975283 hasConceptScore W2061975283C18705241 @default.
- W2061975283 hasConceptScore W2061975283C188027245 @default.
- W2061975283 hasConceptScore W2061975283C198819137 @default.
- W2061975283 hasConceptScore W2061975283C2776294642 @default.
- W2061975283 hasConceptScore W2061975283C2777463227 @default.
- W2061975283 hasConceptScore W2061975283C2780871995 @default.
- W2061975283 hasConceptScore W2061975283C2781144210 @default.
- W2061975283 hasConceptScore W2061975283C32909587 @default.
- W2061975283 hasConceptScore W2061975283C43617362 @default.
- W2061975283 hasConceptScore W2061975283C504270822 @default.
- W2061975283 hasConceptScore W2061975283C55493867 @default.
- W2061975283 hasConceptScore W2061975283C61276311 @default.
- W2061975283 hasConceptScore W2061975283C71240020 @default.
- W2061975283 hasConceptScore W2061975283C8010536 @default.
- W2061975283 hasLocation W20619752831 @default.
- W2061975283 hasOpenAccess W2061975283 @default.
- W2061975283 hasPrimaryLocation W20619752831 @default.
- W2061975283 hasRelatedWork W1520550576 @default.
- W2061975283 hasRelatedWork W1965911231 @default.
- W2061975283 hasRelatedWork W1971945585 @default.
- W2061975283 hasRelatedWork W1973234222 @default.
- W2061975283 hasRelatedWork W1973863953 @default.
- W2061975283 hasRelatedWork W1974832249 @default.
- W2061975283 hasRelatedWork W1978611842 @default.
- W2061975283 hasRelatedWork W1978807552 @default.
- W2061975283 hasRelatedWork W1980612605 @default.
- W2061975283 hasRelatedWork W1982118961 @default.
- W2061975283 hasRelatedWork W2002538797 @default.
- W2061975283 hasRelatedWork W2012490095 @default.
- W2061975283 hasRelatedWork W2017656715 @default.
- W2061975283 hasRelatedWork W2033745462 @default.
- W2061975283 hasRelatedWork W2040592069 @default.
- W2061975283 hasRelatedWork W2052655798 @default.
- W2061975283 hasRelatedWork W2074481786 @default.
- W2061975283 hasRelatedWork W2081338233 @default.
- W2061975283 hasRelatedWork W2130225410 @default.
- W2061975283 hasRelatedWork W2950876569 @default.