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- W2061979524 abstract "The complexes present in freshly-prepared solutions containing cobalt(II) and cyanide ions have been investigated. The main complex is identified as the hexaco-ordinate [Co(CN)5H2O]3– by comparison of its spectrum with those of the analogous isocyanide complexes. No evidence was found for the hexacyanide [Co(CN)6]4– under equilibrium conditions (K6 1 at µ= 2), but another complex, probably the tetracyanide [Co(CN)4(H2O)2]2–, is formed in very dilute solutions. The alkali-metal cations form ion-pairs with the pentacyanide; the ion-pair with Rb+ is identified as [Rb,Co(CN)5H2O]2– and its formation constant in 3N-(Rb,Na)Cl at 20° is 3·7 l./mole. In 3N-LiCl a dimeric complex is also formed. Factors determining the stoicheiometry and stereochemistry of the cobalt(II) complexes with cyanide and isocyanide ligands are discussed." @default.
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- W2061979524 date "1967-01-01" @default.
- W2061979524 modified "2023-09-23" @default.
- W2061979524 title "Low-spin cobalt(II) complexes. Part II. Cyanide complexes" @default.
- W2061979524 doi "https://doi.org/10.1039/j19670001291" @default.
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