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- W2061980663 abstract "(Ether-phosphane)iron(II) Complexes with the Coordination Numbers Four, Five, and Six Photolysis of cis,cis,trans1-Br2(OC)2 Fe(P∑O)2 (1a, b) [O,PPh2PCH2CH2OCH3 (a), Ph2PCH2C4H7O (b)] results in the formation of the iron(II) complexes Br2Fe(P∼O)2 (2a), [BrFe-(P∩O)(μ1-Br)]2 (4b), and [trans1-Br2Fe(P∩O)(μ1-CO)]2 (5a) with the coordination numbers four, five, and six, respectively. 2a crystallizes in the triclinic space group Pdocumentclass{article}pagestyle{empty}begin{document}$bar{1}$end{document} with Z2 and has two monodentated O,P functions (P∼O: η1-P1-coordinated; P∩O:η2-O,P1-coordinated). The dimeric complex 4b with two O∩P-chelated ligands crystallizes in the orthorhombic space group Pbca with Z4. 2a and 4b, which react under CO pressure to give the starting complexes 1a, b, are also accessible from the ether-phosphanes 3a, b and anhydrous FeBr2." @default.
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- W2061980663 date "1993-04-01" @default.
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- W2061980663 title "(Ether‐phosphan)eisen(II)1‐Komplexe mit den Koordinationszahlen Vier, Fünf und Sechs" @default.
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- W2061980663 doi "https://doi.org/10.1002/cber.19931260406" @default.
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