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• W2062003278 abstract "Aliphatic polyesters have been synthesized by enzymatic polymerization of dicarboxylic acids and glycols in a solvent-free system. Candida antarctica lipase catalyzed the polymerization under mild reaction conditions, despite the heterogeneous mixture of the monomers and catalyst. Effects of the polymerization conditions were systematically investigated in the polymerization of sebacic acid and 1,4-butanediol. Methylene chain length of the monomers greatly affected the polymer yield and molecular weight. The polymer with molecular weight of more than 1×104 was obtained by the reaction under reduced pressure. The addition of a small amount of adjuvant afforded the polymer from the solid monomers." @default.
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• W2062003278 date "2000-05-01" @default.
• W2062003278 modified "2023-09-30" @default.
• W2062003278 title "Lipase-Catalyzed Synthesis of Aliphatic Polyesters by Polycondensation of Dicarboxylic Acids and Glycols in Solvent-Free System" @default.
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• W2062003278 doi "https://doi.org/10.1295/polymj.32.440" @default.
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