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- W2062018319 abstract "This paper describes the extraction of C5–C8 linear α-olefins from olefin/paraffin mixtures of the same carbon number using silver(I)/N,N-dimethylbenzamide bis(trifluoromethylsulfonyl)imide ([Ag(DMBA)2][Tf2N]) or silver(I)/propylamine bis(trifluoromethylsulfonyl)imide ([Ag(PrNH2)2][Tf2N]) as the extracting agent. The separation performance of the system increased with increasing chain length. [Ag(DMBA)2][Tf2N] appeared to outperform [Ag(PrNH2)2][Tf2N] in terms of both selectivity and distribution coefficient. The [Ag(DMBA)2][Tf2N] system was successfully modeled using the universal quasi-chemical activity coefficient (UNIQUAC) model. These results support the potential future development of amine/amide-based ligands for producing soluble silver complexes useful for the separation of olefins from paraffins." @default.
- W2062018319 created "2016-06-24" @default.
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- W2062018319 date "2014-11-15" @default.
- W2062018319 modified "2023-10-18" @default.
- W2062018319 title "Enhancing Liquid-Phase Olefin–Paraffin Separations Using Novel Silver-Based Ionic Liquids" @default.
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- W2062018319 doi "https://doi.org/10.1021/je5004669" @default.
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