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• W2062074468 abstract "An analysis of the π-electronic topology of a recently reported pentadecanuclear manganese metallacycle in terms of linking number, twist, and writhe confirms its previous assignment as a Möbius system of order six. The total degree of local torsion is reduced by a significant contribution from writhe, thus correcting the previously inferred local torsion at each metal center from 120° to ∼90°. This latter value suggests a model for the cyclic π conjugation around the metallacycle, which involves 3dπ−2pπ interactions at the metal center, of a type first suggested by Craig 50 years ago in the context of main group cyclic aromatic systems." @default.
• W2062074468 created "2016-06-24" @default.
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• W2062074468 date "2008-08-21" @default.
• W2062074468 modified "2023-10-01" @default.
• W2062074468 title "Linking Number Analysis of a Pentadecanuclear Metallamacrocycle: A Möbius-Craig System Revealed" @default.
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• W2062074468 doi "https://doi.org/10.1021/ic800987f" @default.
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