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- W2062078401 abstract "Adducts of the M(guH)Cl2 type were prepared by refluxing 2:1 molar mixtures of guanine (guH) and MCl2 (M = Co, Cu, Zn) in ethanol-triethyl orthoformate for 2–3 days. Characterization studies suggest that all three new complexes involve distorted tetrahedral configurations. A linear chainlike polymeric structural type with a single-bridged (-MguH-)n backbone and two terminal chloro ligands per metal ion (MN2Cl2 chromophore) is proposed for these compounds, in view of their poor solubility in organic media, their stoichiometry in conjunction with their tetrahedral symmetry, and the reported crystal structures of 9-methyladenine analogs (M = Co, Zn), which are polymeric with single bridges of the adenine derivative between adjacent metal ions. Bidentate bridging guH coordinates exclusively through ring nitrogens, and is most probably N(7), N(9)-bonded. The possibility of use of exocyclic potential ligand sites of guH (CO oxygen or NH2 nitrogen) in coordination is ruled out by the infrared evidence [1]." @default.
- W2062078401 created "2016-06-24" @default.
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- W2062078401 date "1985-05-01" @default.
- W2062078401 modified "2023-09-26" @default.
- W2062078401 title "Tetrahedral 1:1 adducts of guanine with cobalt(II), copper(II) and zinc(II) chlorides" @default.
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- W2062078401 doi "https://doi.org/10.1016/s0020-1693(00)80694-5" @default.
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