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- W2062111566 abstract "In aqueous solutions, hydrogen chloride adds to cis-chloro(allylamine)bis(ethylenediamine)cobalt(III) chloride to give a mixture of 42%cis-chloro-(β-chloro-n-propylamine)bis(ethylenediamine)cobalt(III) chloride and 58%cis-chloro-(γ-chloro-n-propylamine)bis(ethylenediamine)cobalt(III) chloride. Hydrogen bromide reacts with the corresponding bromo-complex similarly, giving 38%cis-bromo-(β-bromo-n-propylamine)bis(ethylenediamine)cobalt(III) bromide and 62%cis-bromo-(γ-bromo-n-propylamine)bis(ethylenediamine)cobalt(III) bromide. Each mole of the corresponding cis-chloro(propargylamine) complex takes up two moles of hydrogen chloride, but each mole of the bromo-analogue can only take up one mole of hydrogen bromide." @default.
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- W2062111566 date "1968-01-01" @default.
- W2062111566 modified "2023-09-25" @default.
- W2062111566 title "Ligand reactions. Part II. The addition of hydrogen halides to some unsaturated aliphatic amines co-ordinated to cobalt(III)" @default.
- W2062111566 doi "https://doi.org/10.1039/j19680000136" @default.
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