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• W2062118466 abstract "Adsorption and reactivity of carbon dioxide at the clean and oxygen precovered Ni(110) surface has been studied by means of EELS and LEED. On the clean surface two different types of CO2 molecules have been observed by EELS at 135 K, one being the undisturbed linear configuration. With increasing temperature the linear molecule changes into a different species which precedes dissociation at 220 K into CO and O. EELS and LEED data of the intermediate species support the assumption that it is a bent CO−2 anion adsorbed in C2v symmetry with twofold oxygen coordination to the surface. Oxygen preadsorption stabilizes the linear CO2 molecule up to higher temperatures which does not convert into a bent species in this case. Instead, a reaction product of CO2 and O is found and interpreted as a carbonate species." @default.
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• W2062118466 date "1987-01-01" @default.
• W2062118466 modified "2023-09-23" @default.
• W2062118466 title "Reactivity of carbon dioxide at nickel (110)" @default.
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• W2062118466 doi "https://doi.org/10.1016/0368-2048(87)87015-9" @default.
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