FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2062181040> ?p ?o ?g. }

• W2062181040 endingPage "879" @default.
• W2062181040 startingPage "868" @default.
• W2062181040 abstract "Biotechnologically accessible 1,4-butanediol and vegetal oil-based diethyl sebacate were copolymerized with bicyclic acetalized d-glucose derivatives (Glux) by polycondensation both in the melt at high temperature and in solution at mild temperature mediated by polymer-supported Candida antarctica lipase B (CALB). Two series of random copolyesters (PBxGluxySeb and PBSebxGluxy) were prepared differing in which d-glucose derivative (Glux diol or Glux diester) was used as comonomer. The three parent homopolyesters PBSeb, PBGlux, and PGluxSeb were prepared as well. Both methods were found to be effective for polymerization although significant higher molecular weights were achieved by melt polycondensation. The thermal properties displayed by the copolyesters were largely dependent on composition and also on the functionality of the replacing Glux unit. The thermal stability of PBSeb was retained or even slightly increased after copolymerization with Glux, whereas crystallinity and melting temperature were largely depressed. On the contrary, the glass-transition temperature noticeably increased with the content in Glux units. PGluxSeb distinguished in displaying both Tg and Tm higher than PBSeb because a different crystal structure is adopted by this homopolyester. The hydrolytic degradability of PBSeb in water was enhanced by copolymerization, in particular, when biodegradation was assisted by lipases." @default.
• W2062181040 created "2016-06-24" @default.
• W2062181040 creator A5014479852 @default.
• W2062181040 creator A5031437729 @default.
• W2062181040 creator A5035261462 @default.
• W2062181040 creator A5042616175 @default.
• W2062181040 creator A5044589453 @default.
• W2062181040 creator A5069044527 @default.
• W2062181040 date "2015-02-11" @default.
• W2062181040 modified "2023-10-10" @default.
• W2062181040 title "Copolyesters Made from 1,4-Butanediol, Sebacic Acid, and <scp>d</scp>-Glucose by Melt and Enzymatic Polycondensation" @default.
• W2062181040 cites W1510441480 @default.
• W2062181040 cites W1978054181 @default.
• W2062181040 cites W1978085745 @default.
• W2062181040 cites W1981284405 @default.
• W2062181040 cites W1987370064 @default.
• W2062181040 cites W1990374045 @default.
• W2062181040 cites W1992248393 @default.
• W2062181040 cites W2000219349 @default.
• W2062181040 cites W2015703106 @default.
• W2062181040 cites W2017992601 @default.
• W2062181040 cites W2018017628 @default.
• W2062181040 cites W2022458510 @default.
• W2062181040 cites W2025768853 @default.
• W2062181040 cites W2032694371 @default.
• W2062181040 cites W2040801068 @default.
• W2062181040 cites W2052429898 @default.
• W2062181040 cites W2068875102 @default.
• W2062181040 cites W2073972816 @default.
• W2062181040 cites W2123921087 @default.
• W2062181040 cites W2140924325 @default.
• W2062181040 cites W2141094946 @default.
• W2062181040 cites W2158714891 @default.
• W2062181040 cites W2162365515 @default.
• W2062181040 cites W2170014999 @default.
• W2062181040 cites W2238658591 @default.
• W2062181040 cites W2318157103 @default.
• W2062181040 cites W2321571472 @default.
• W2062181040 cites W2487823518 @default.
• W2062181040 doi "https://doi.org/10.1021/bm501771e" @default.
• W2062181040 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/25621935" @default.
• W2062181040 hasPublicationYear "2015" @default.
• W2062181040 type Work @default.
• W2062181040 sameAs 2062181040 @default.
• W2062181040 citedByCount "55" @default.
• W2062181040 countsByYear W20621810402015 @default.
• W2062181040 countsByYear W20621810402016 @default.
• W2062181040 countsByYear W20621810402017 @default.
• W2062181040 countsByYear W20621810402018 @default.
• W2062181040 countsByYear W20621810402019 @default.
• W2062181040 countsByYear W20621810402020 @default.
• W2062181040 countsByYear W20621810402021 @default.
• W2062181040 countsByYear W20621810402022 @default.
• W2062181040 countsByYear W20621810402023 @default.
• W2062181040 crossrefType "journal-article" @default.
• W2062181040 hasAuthorship W2062181040A5014479852 @default.
• W2062181040 hasAuthorship W2062181040A5031437729 @default.
• W2062181040 hasAuthorship W2062181040A5035261462 @default.
• W2062181040 hasAuthorship W2062181040A5042616175 @default.
• W2062181040 hasAuthorship W2062181040A5044589453 @default.
• W2062181040 hasAuthorship W2062181040A5069044527 @default.
• W2062181040 hasBestOaLocation W20621810402 @default.
• W2062181040 hasConcept C100544194 @default.
• W2062181040 hasConcept C119394753 @default.
• W2062181040 hasConcept C122865956 @default.
• W2062181040 hasConcept C15920480 @default.
• W2062181040 hasConcept C178790620 @default.
• W2062181040 hasConcept C181199279 @default.
• W2062181040 hasConcept C185592680 @default.
• W2062181040 hasConcept C188027245 @default.
• W2062181040 hasConcept C2776407124 @default.
• W2062181040 hasConcept C2778160795 @default.
• W2062181040 hasConcept C2779123355 @default.
• W2062181040 hasConcept C2779515768 @default.
• W2062181040 hasConcept C2779542420 @default.
• W2062181040 hasConcept C2779697368 @default.
• W2062181040 hasConcept C2780672802 @default.
• W2062181040 hasConcept C44228677 @default.
• W2062181040 hasConcept C46275449 @default.
• W2062181040 hasConcept C521977710 @default.
• W2062181040 hasConcept C53033327 @default.
• W2062181040 hasConcept C59061564 @default.
• W2062181040 hasConcept C8010536 @default.
• W2062181040 hasConcept C94412978 @default.
• W2062181040 hasConceptScore W2062181040C100544194 @default.
• W2062181040 hasConceptScore W2062181040C119394753 @default.
• W2062181040 hasConceptScore W2062181040C122865956 @default.
• W2062181040 hasConceptScore W2062181040C15920480 @default.
• W2062181040 hasConceptScore W2062181040C178790620 @default.
• W2062181040 hasConceptScore W2062181040C181199279 @default.
• W2062181040 hasConceptScore W2062181040C185592680 @default.
• W2062181040 hasConceptScore W2062181040C188027245 @default.
• W2062181040 hasConceptScore W2062181040C2776407124 @default.
• W2062181040 hasConceptScore W2062181040C2778160795 @default.
• W2062181040 hasConceptScore W2062181040C2779123355 @default.
• W2062181040 hasConceptScore W2062181040C2779515768 @default.
• W2062181040 hasConceptScore W2062181040C2779542420 @default.
• W2062181040 hasConceptScore W2062181040C2779697368 @default.

• next