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• W2062185832 startingPage "627" @default.
• W2062185832 abstract "Monte Carlo simulations for the adsorption of symmetric triblock copolymers from a nonselective solvent at a solid–liquid interface have been performed on a lattice model. In simulations, triblock copolymer molecules are modeled as self-avoiding linear chains composed of m segments of A and n segments of B arranged as Am/2BnAm/2. Either segment A or segment B is attractive, while the other is non-attractive to the surface. The microstructure of the adsorbed layers, including the segment-density profiles and the size distribution of loops, tails and trains are presented. The effect of the adsorption energy, the bulk concentration, the chain composition, as well as the chain length on various adsorption properties has been studied. The results have shown that the size distribution of various configurations is dependent of the adsorption energy, the chain composition and the chain length. The mean length of the loops, trains and tails is insensitive to the bulk concentration. The mean length of the trains increases and that of the tails decreases as the adsorption energy and the length of the attractive segments increase. The mean length of the loops for the end-adsorbed copolymers appears a maximum and that for middle-adsorbed copolymers appears a minimum as the length of attractive segments increases. The length of the non-attractive segments affects mostly the size distribution of the tails. The longer the chain is, the larger the tail appears. The mean length of the tails and loops increases linearly as the length of the non-attractive segments increases, but that of the trains approximately is unchanged." @default.
• W2062185832 created "2016-06-24" @default.
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• W2062185832 date "2005-03-01" @default.
• W2062185832 modified "2023-10-16" @default.
• W2062185832 title "Monte Carlo simulation for the adsorption of symmetric triblock copolymers I. Configuration distribution and density profiles of adsorbed chains" @default.
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• W2062185832 doi "https://doi.org/10.1016/j.eurpolymj.2004.10.025" @default.
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