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- W2062246670 abstract "Reaction of equimolar amounts of the ferriophosphaalkene Cp*(CO)2FePC(Ph)NMe2 (1a) and fumarodinitrile in diethyl ether afforded the ferriophosphetane (2a). Analogously, Cp*(CO)2FePC(tBu)NMe2 (1b) was converted into (2b). Evidence for the cyclic structure of 2a,b in the crystal was provided by the X-ray structural analysis of 2a. Whereas the phosphetane ring of 2b is retained in solution, product 2a in CH2Cl2 solution underwent an isomerization to give the acyclic secondary ferriophosphane Cp*(CO)2Fe−P(H)−CH(CN)−C(CN)C(Ph)NMe2 (3a) as a mixture of isomers. The ferriophosphane Cp*(CO)2FeP[CH(CN)−CH2CN][CH(CN)−C(CN)C(tBu)NMe2] (5) was isolated in less than 1% yield from the reaction of 1b and the alkene. The reaction of ferrioarsaalkene Cp*(CO)2FeAsC(Ph)NMe2 (6) and fumaronitrile gave rise to the formation of the ferrioarsetane (7), which unlike 2a resists ring opening in solution." @default.
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- W2062246670 date "2002-04-04" @default.
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- W2062246670 title "Fumarodinitrile: A Versatile Reagent in Phosphaalkene and Arsaalkene Chemistry" @default.
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- W2062246670 doi "https://doi.org/10.1021/om010990c" @default.
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