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• W2062288013 abstract "A nanoscale icosahedral quasicrystalline phase formation was found by the slight deviation from the three-component rule for high glass-forming ability in a Zr 65 Al 7.5 Ni 10 Cu 17.5 glassy alloy. Since the primary phase consists of fcc Zr 2 Ni and I-phases in the Zr 65 Al 7.5 Ni 10 Cu 16.5 (Ag, Pd, Au or Pt) 1 glassy alloys, where an icosahedron is contained in both the phases, it is suggested that the local icosahedral atomic configuration exists in the glassy state and it stabilizes the supercooled liquid state. We also clarified that an I-phase precipitates in the Zr 70 Cu 29 Pd 1 and Zr 70 Ni 20 Al 9 Pd 1 glassy alloys and no I-phase formation is observed in the Zr 70 Ni 29 Pd 1 amorphous alloy. Since the supercooled liquid region is confirmed in the Zr 70 Cu 30 and Zr 70 Ni 20 Al 10 glassy alloys and is not observed in the Zr 70 Ni 30 amorphous alloy, it is concluded that the stability of the supercooled liquid state is strongly correlated with the existence of the local icosahedral order." @default.
• W2062288013 created "2016-06-24" @default.
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• W2062288013 date "2002-11-01" @default.
• W2062288013 modified "2023-09-24" @default.
• W2062288013 title "Nano icosahedral quasicrystals in Zr-based glassy alloys" @default.
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• W2062288013 doi "https://doi.org/10.1016/s0966-9795(02)00142-5" @default.
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