FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2062297608> ?p ?o ?g. }

• W2062297608 abstract "Abstract Chlorine-35 NQR frequencies, ν, for (Cl 3 PN R ) 2 , where R = CH 3 , C 2 H 5 , or Ph, and for (ClOPNCH 3 ) 2 have been measured over the temperature range 77 ⩽ T ⩽ 350 K. Chlorine-35 asymmetry parameters have been measured for (Cl 3 PNCH 3 ) 2 at 295 K, and they show that π-character cannot contribute any more than 1–2% to the nature of the PCl bonds in this molecule. Chlorine-35 NQR frequencies for (Cl 3 PN R ) 2 , where R = CH 3 or Ph, also have been measured over the pressure range 1 ⩽ P ⩽ 1500 Kg cm −2 , at 295 K. These measurements enable three methods to be used to distinguish axial from equatorial chlorine atoms. Their resonance frequencies are different, the temperature coefficients of these frequencies are different, and the pressure coefficients of these frequencies are different. The partial differential coefficients have been evaluated for (Cl 3 PN R ) 2 , where R = CH 3 and Ph. Bayer-type analyses show that the characteristic effects of temperature and pressure on these compounds originate in the typical ionic characters of the PCl bonds and in the characteristic 64 cm −1 PCl 3 torsional-bending modes in these solids. The analyses also indicate that it should be possible to distinguish between different kinds of PCl systems by measuring the effects of applied pressures or changes in temperature on their chlorine-35 NQR frequencies." @default.
• W2062297608 created "2016-06-24" @default.
• W2062297608 creator A5041619862 @default.
• W2062297608 creator A5051569557 @default.
• W2062297608 date "1975-11-01" @default.
• W2062297608 modified "2023-09-23" @default.
• W2062297608 title "Chlorine-35 nuclear quadrupole resonance spectra of the chlorocyclodiphosphazanes (Cl3PNR)2 and of the chlorooxocyclodiphosphazanes (ClOPNR)2" @default.
• W2062297608 cites W1677645840 @default.
• W2062297608 cites W1967526215 @default.
• W2062297608 cites W1969585344 @default.
• W2062297608 cites W1971570208 @default.
• W2062297608 cites W1979845147 @default.
• W2062297608 cites W1979970753 @default.
• W2062297608 cites W1984583862 @default.
• W2062297608 cites W1991763845 @default.
• W2062297608 cites W1996246641 @default.
• W2062297608 cites W1996345452 @default.
• W2062297608 cites W2013025903 @default.
• W2062297608 cites W2013917859 @default.
• W2062297608 cites W2020532527 @default.
• W2062297608 cites W2036555611 @default.
• W2062297608 cites W2047725676 @default.
• W2062297608 cites W2055861258 @default.
• W2062297608 cites W2074996826 @default.
• W2062297608 cites W2077847602 @default.
• W2062297608 cites W2086351730 @default.
• W2062297608 cites W2086725314 @default.
• W2062297608 cites W2091839757 @default.
• W2062297608 cites W2099069835 @default.
• W2062297608 cites W2109790350 @default.
• W2062297608 cites W2120020014 @default.
• W2062297608 cites W590866981 @default.
• W2062297608 doi "https://doi.org/10.1016/0022-2364(75)90260-7" @default.
• W2062297608 hasPublicationYear "1975" @default.
• W2062297608 type Work @default.
• W2062297608 sameAs 2062297608 @default.
• W2062297608 citedByCount "5" @default.
• W2062297608 crossrefType "journal-article" @default.
• W2062297608 hasAuthorship W2062297608A5041619862 @default.
• W2062297608 hasAuthorship W2062297608A5051569557 @default.
• W2062297608 hasConcept C113196181 @default.
• W2062297608 hasConcept C121332964 @default.
• W2062297608 hasConcept C1276947 @default.
• W2062297608 hasConcept C139210041 @default.
• W2062297608 hasConcept C145148216 @default.
• W2062297608 hasConcept C155647269 @default.
• W2062297608 hasConcept C178790620 @default.
• W2062297608 hasConcept C184779094 @default.
• W2062297608 hasConcept C185592680 @default.
• W2062297608 hasConcept C2182769 @default.
• W2062297608 hasConcept C2778981401 @default.
• W2062297608 hasConcept C2993530813 @default.
• W2062297608 hasConcept C30545975 @default.
• W2062297608 hasConcept C32909587 @default.
• W2062297608 hasConcept C39353612 @default.
• W2062297608 hasConcept C39984356 @default.
• W2062297608 hasConcept C46141821 @default.
• W2062297608 hasConcept C4839761 @default.
• W2062297608 hasConcept C505241676 @default.
• W2062297608 hasConcept C97355855 @default.
• W2062297608 hasConceptScore W2062297608C113196181 @default.
• W2062297608 hasConceptScore W2062297608C121332964 @default.
• W2062297608 hasConceptScore W2062297608C1276947 @default.
• W2062297608 hasConceptScore W2062297608C139210041 @default.
• W2062297608 hasConceptScore W2062297608C145148216 @default.
• W2062297608 hasConceptScore W2062297608C155647269 @default.
• W2062297608 hasConceptScore W2062297608C178790620 @default.
• W2062297608 hasConceptScore W2062297608C184779094 @default.
• W2062297608 hasConceptScore W2062297608C185592680 @default.
• W2062297608 hasConceptScore W2062297608C2182769 @default.
• W2062297608 hasConceptScore W2062297608C2778981401 @default.
• W2062297608 hasConceptScore W2062297608C2993530813 @default.
• W2062297608 hasConceptScore W2062297608C30545975 @default.
• W2062297608 hasConceptScore W2062297608C32909587 @default.
• W2062297608 hasConceptScore W2062297608C39353612 @default.
• W2062297608 hasConceptScore W2062297608C39984356 @default.
• W2062297608 hasConceptScore W2062297608C46141821 @default.
• W2062297608 hasConceptScore W2062297608C4839761 @default.
• W2062297608 hasConceptScore W2062297608C505241676 @default.
• W2062297608 hasConceptScore W2062297608C97355855 @default.
• W2062297608 hasLocation W20622976081 @default.
• W2062297608 hasOpenAccess W2062297608 @default.
• W2062297608 hasPrimaryLocation W20622976081 @default.
• W2062297608 hasRelatedWork W1965250239 @default.
• W2062297608 hasRelatedWork W1971146904 @default.
• W2062297608 hasRelatedWork W1974189873 @default.
• W2062297608 hasRelatedWork W1977604260 @default.
• W2062297608 hasRelatedWork W1978904236 @default.
• W2062297608 hasRelatedWork W2004219584 @default.
• W2062297608 hasRelatedWork W2025250822 @default.
• W2062297608 hasRelatedWork W2039906426 @default.
• W2062297608 hasRelatedWork W2045576676 @default.
• W2062297608 hasRelatedWork W2064909924 @default.
• W2062297608 hasRelatedWork W2064967078 @default.
• W2062297608 hasRelatedWork W2071820426 @default.
• W2062297608 hasRelatedWork W2074037390 @default.
• W2062297608 hasRelatedWork W2080155363 @default.
• W2062297608 hasRelatedWork W2081142214 @default.
• W2062297608 hasRelatedWork W2082235745 @default.
• W2062297608 hasRelatedWork W2088555371 @default.

• next