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- W2062328293 abstract "The intermetallic compound CaNi5 disproportionates rapidly into CaH2 and Ni when treated with hydrogen above 350° C. The kinetics of this reaction in the initial stages follows the nucleation and growth mechanism. The pressure-composition-temperature isotherms for hydrogen interaction with CaNi5 in the temperature range 640°C to 725°C have been determined and the ΔHf for CaNi5 is calculated to be 12.9 kcal/mol. Differential thermal analysis confirms the scheme proposed for the CaNi5-H2 reaction. Even a 5% disproportionation of the alloy drastically affects the kinetics of hydrogen Sorption at room temperature." @default.
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- W2062328293 date "1988-10-01" @default.
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- W2062328293 title "High temperature interaction of hydrogen with intermetallic compound CaNi5" @default.
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- W2062328293 doi "https://doi.org/10.1016/0254-0584(88)90064-8" @default.
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