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- W2062334114 abstract "Abstract Metalloligands L1 and L2 consisting of directional bis(terpyridine)ruthenium(II) units and bipyridine moieties were constructed by amide formation. From these metalloligands two Ru–Pt heterobimetallic complexes 1 and 2 were derived by a building‐block method by means of platination with [PtCl 2 (dmso) 2 ]. Both bimetallic complexes 1 and 2 feature metal‐to‐ligand charge transfer (MLCT) absorptions, and emission occurs at room temperature in fluid solution from 3 MLCT(Ru) states in all cases. Energy transfer from platinum to ruthenium is observed in 2 but not in 1 (light harvesting). The one‐electron‐reduced species [ 1 ] – and [ 2 ] – were prepared by reduction of 1 and 2 with decamethylcobaltocene. EPR spectra and DFT calculations reveal that the spin density is localized at the tpy–CO/Ru (tpy = terpyridine) site in [ 1 ] – , whereas it is centered at bpy–CO/Pt (bpy = 2,2′‐bipyridine) in [ 2 ] – . Efficient photoinduced electron transfer from triethanolamine to 1 and 2 is feasible by excitation at 500 nm [MLCT(Ru)]." @default.
- W2062334114 created "2016-06-24" @default.
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- W2062334114 date "2013-04-25" @default.
- W2062334114 modified "2023-10-16" @default.
- W2062334114 title "Thermal and Photoinduced Electron Transfer in Directional Bis(terpyridine)ruthenium(II)–(Bipyridine)platinum(II) Complexes" @default.
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- W2062334114 doi "https://doi.org/10.1002/ejic.201201531" @default.
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