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- W2062352181 abstract "Bulk and surface changes in two proton-exchange membranes (Nafion-112 and Nafion-117) as a result of the incorporation of the IL-cation n -dodecyltriethylammonium (or DTA + ) by a proton/cation exchange mechanism after immersion in a DTA + aqueous solution were analysed by impedance spectroscopy (IS), differential scanning calorimetry (DSC), X-ray photoelectron spectroscopy (XPS), and contact angle measurements performed with dry samples of the original Nafion and Nafion-DTA + -modified membranes. Only slight differences were obtained in the incorporation degree and surface chemical nature depending on the membrane thickness, and DTA + incorporation modified both the hydrophobic character of the original Nafion membranes and their thermal stability. Electrical characterization of the dry Nafion-112 membrane was performed by impedance spectroscopy while different HCl solutions were used for membrane potential measurements. A study of time evolution of the impedance curves measured in the system “IL aqueous solution/Nafion-112 membrane/IL aqueous solution” was also performed. This study allows us monitoring the electrical changes associated to the IL-cation incorporation in both the membrane and the membrane/IL solution interface, and it provides supplementary information on the characteristic of the Nafion/DTA + hybrid material. Moreover, the results also show the significant effect of water on the electrical resistance of the Nafion-112/IL-cation-modified membrane." @default.
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- W2062352181 date "2012-01-01" @default.
- W2062352181 modified "2023-10-17" @default.
- W2062352181 title "Modification of Nafion Membranes by IL-Cation Exchange: Chemical Surface, Electrical and Interfacial Study" @default.
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- W2062352181 doi "https://doi.org/10.1155/2012/349435" @default.
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