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- W2062352433 abstract "Complexation of non-mesomorphic dithiooxamide ligands to Pt(II) leads to square planar complexes which exhibit mesomorphic properties. The synthesis of these complexes was accomplished in three steps: the formation of bisamides, starting from conveniently substituted anilines, their conversion into dithiooxamides and the reaction of these sulfur derivatives with [PtCl2(dmso)2]. Four, eight and twelve-chained complexes were obtained and their behaviour as potentially mesomorphic material was studied. The eight-chained complexes 21 (n = 12–16) and the twelve-chained complexes 22 (n = 8,11,13) exhibit columnar mesophases which have been characterised by optical microscopy, X-ray scattering and related miscibility studies." @default.
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- W2062352433 date "2000-08-01" @default.
- W2062352433 modified "2023-09-27" @default.
- W2062352433 title "Mesomorphic Dithiooxamide Complexes of Platinum(II)" @default.
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- W2062352433 doi "https://doi.org/10.1080/10587250008024795" @default.
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