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- W2062362811 abstract "The infrared spectra of the vapour above AlCl3(s) under saturated as well as superheated conditions have been measured. From the results for the saturated-vapour phase the infrared-active vibrational wavenumbers of Al2Cl6 have been obtained. In the superheated vapour above AlCl3, an appreciable amount of monomeric molecules was found, enabling the assignment of the three infrared-active fundamentals of AlCl3(g). Combining the results with quantities from the literature, the thermal functions of AlCl3(g) and Al2Cl6(g) have been calculated, yielding for the standard molar entropies S°m(AlCl3, g, 298.15 K) = (312.7 ± 2.0) J·K−1·mol−1 and S°m(Al2Cl6,g,298.15 K) = (470.2 ± 3.0) J·K−1·mol−1. Third-law evaluation of the available vapour pressures yielded ΔfH°m(AlCl3,g,298.15 K) = −(585.7±1.8)kJ·mol−1 and ΔfH·m(Al2Cl6,g,298.15 K) = −(1299.0±1.9)kJ·mol−1." @default.
- W2062362811 created "2016-06-24" @default.
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- W2062362811 date "1992-11-01" @default.
- W2062362811 modified "2023-10-05" @default.
- W2062362811 title "High-temperature i.r. spectroscopy of the vapour over AlCl3 The thermodynamic properties of AlCl3(g) and Al2Cl6(g)" @default.
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- W2062362811 doi "https://doi.org/10.1016/s0021-9614(05)80242-3" @default.
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