FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2062412769> ?p ?o ?g. }

• W2062412769 endingPage "9437" @default.
• W2062412769 startingPage "9425" @default.
• W2062412769 abstract "New examples of [C6F5Xe]+ salts of the weakly coordinating anions [B(CF3)4]-, [B(C6F5)4]-, [B(CN)4]-, and [B(OTeF5)4]- have been synthesized by metathesis reactions of [C6F5Xe][BF4] with the corresponding MI[BY4] salts (MI = K or Cs; Y = CF3, C6F5, CN, or OTeF5). The salts were characterized in solution by multi-NMR spectroscopy. Their stabilities in prototypic solvents (CH3CN and CH2Cl2) and decomposition products are reported. The influence of the coordinating nature of [BY4]- on the decomposition rate of [C6F5Xe]+ as well as the presence of the weakly nucleophilic [BF4]- ion has been studied. The electrophilic pentafluorophenylation of C6H5F by [C6F5Xe][BY4] in solvents of different coordinating abilities (CH3CN and CH2Cl2) and the effects of stronger nucleophiles (fluoride and water) on the pentafluorophenylation process have been investigated. Simulations of the 19F and 129Xe NMR spectra of [C6F5Xe]+ have provided the complete set of aryl 19F−19F and 129Xe−19F coupling constants and their relative signs. The 19F NMR parameters of the [C6F5Xe]+ cation in the present series of salts are shown to reflect the relative degrees of cation−solvent interactions." @default.
• W2062412769 created "2016-06-24" @default.
• W2062412769 creator A5014839460 @default.
• W2062412769 creator A5022346082 @default.
• W2062412769 creator A5044788359 @default.
• W2062412769 creator A5044585145 @default.
• W2062412769 creator A5051243131 @default.
• W2062412769 date "2007-09-29" @default.
• W2062412769 modified "2023-09-26" @default.
• W2062412769 title "Syntheses, Solution Multi-NMR Characterization, and Reactivities of [C₆F₅Xe]⁺ Salts of Weakly Coordinating Borate Anions, [BY₄]^- (Y = CF₃, C₆F₅, CN, or OTeF₅)" @default.
• W2062412769 cites W1548160774 @default.
• W2062412769 cites W1977134660 @default.
• W2062412769 cites W1986539704 @default.
• W2062412769 cites W1994927385 @default.
• W2062412769 cites W1999029225 @default.
• W2062412769 cites W2015258059 @default.
• W2062412769 cites W2030623412 @default.
• W2062412769 cites W2062478966 @default.
• W2062412769 cites W2068734673 @default.
• W2062412769 cites W2081324224 @default.
• W2062412769 cites W2087306974 @default.
• W2062412769 cites W2087883457 @default.
• W2062412769 cites W2088985121 @default.
• W2062412769 cites W2150425178 @default.
• W2062412769 cites W2319022792 @default.
• W2062412769 cites W2949229825 @default.
• W2062412769 doi "https://doi.org/10.1021/ic7010138" @default.
• W2062412769 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/17902647" @default.
• W2062412769 hasPublicationYear "2007" @default.
• W2062412769 type Work @default.
• W2062412769 sameAs 2062412769 @default.
• W2062412769 citedByCount "30" @default.
• W2062412769 countsByYear W20624127692012 @default.
• W2062412769 countsByYear W20624127692013 @default.
• W2062412769 countsByYear W20624127692014 @default.
• W2062412769 countsByYear W20624127692015 @default.
• W2062412769 countsByYear W20624127692017 @default.
• W2062412769 countsByYear W20624127692018 @default.
• W2062412769 countsByYear W20624127692019 @default.
• W2062412769 countsByYear W20624127692020 @default.
• W2062412769 countsByYear W20624127692022 @default.
• W2062412769 countsByYear W20624127692023 @default.
• W2062412769 crossrefType "journal-article" @default.
• W2062412769 hasAuthorship W2062412769A5014839460 @default.
• W2062412769 hasAuthorship W2062412769A5022346082 @default.
• W2062412769 hasAuthorship W2062412769A5044585145 @default.
• W2062412769 hasAuthorship W2062412769A5044788359 @default.
• W2062412769 hasAuthorship W2062412769A5051243131 @default.
• W2062412769 hasConcept C116447816 @default.
• W2062412769 hasConcept C121332964 @default.
• W2062412769 hasConcept C124681953 @default.
• W2062412769 hasConcept C1276947 @default.
• W2062412769 hasConcept C153914509 @default.
• W2062412769 hasConcept C155647269 @default.
• W2062412769 hasConcept C161790260 @default.
• W2062412769 hasConcept C178790620 @default.
• W2062412769 hasConcept C178907741 @default.
• W2062412769 hasConcept C179104552 @default.
• W2062412769 hasConcept C185592680 @default.
• W2062412769 hasConcept C2780263894 @default.
• W2062412769 hasConcept C2780471494 @default.
• W2062412769 hasConcept C2780828025 @default.
• W2062412769 hasConcept C2781076698 @default.
• W2062412769 hasConcept C44228677 @default.
• W2062412769 hasConcept C4839761 @default.
• W2062412769 hasConcept C50027330 @default.
• W2062412769 hasConcept C501308230 @default.
• W2062412769 hasConcept C521977710 @default.
• W2062412769 hasConcept C66974803 @default.
• W2062412769 hasConcept C67787023 @default.
• W2062412769 hasConcept C71240020 @default.
• W2062412769 hasConceptScore W2062412769C116447816 @default.
• W2062412769 hasConceptScore W2062412769C121332964 @default.
• W2062412769 hasConceptScore W2062412769C124681953 @default.
• W2062412769 hasConceptScore W2062412769C1276947 @default.
• W2062412769 hasConceptScore W2062412769C153914509 @default.
• W2062412769 hasConceptScore W2062412769C155647269 @default.
• W2062412769 hasConceptScore W2062412769C161790260 @default.
• W2062412769 hasConceptScore W2062412769C178790620 @default.
• W2062412769 hasConceptScore W2062412769C178907741 @default.
• W2062412769 hasConceptScore W2062412769C179104552 @default.
• W2062412769 hasConceptScore W2062412769C185592680 @default.
• W2062412769 hasConceptScore W2062412769C2780263894 @default.
• W2062412769 hasConceptScore W2062412769C2780471494 @default.
• W2062412769 hasConceptScore W2062412769C2780828025 @default.
• W2062412769 hasConceptScore W2062412769C2781076698 @default.
• W2062412769 hasConceptScore W2062412769C44228677 @default.
• W2062412769 hasConceptScore W2062412769C4839761 @default.
• W2062412769 hasConceptScore W2062412769C50027330 @default.
• W2062412769 hasConceptScore W2062412769C501308230 @default.
• W2062412769 hasConceptScore W2062412769C521977710 @default.
• W2062412769 hasConceptScore W2062412769C66974803 @default.
• W2062412769 hasConceptScore W2062412769C67787023 @default.
• W2062412769 hasConceptScore W2062412769C71240020 @default.
• W2062412769 hasIssue "22" @default.
• W2062412769 hasLocation W20624127691 @default.
• W2062412769 hasLocation W20624127692 @default.
• W2062412769 hasOpenAccess W2062412769 @default.

• next