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- W2062425107 abstract "This paper describes the complete assignment of the 183W NMR spectra of the chiral polyoxometalates α1-[P2W17O61]10- and α1-[YbP2W17O61]7- in aqueous solution. These spectra display each 17 lines of equal intensity with a relatively narrow chemical shift distribution. The identification of signals is based on selective 31P−183W decoupling and recognition of particular sets of coupling constants for tungsten atoms around the lacunary site. Further assignment is obtained by 183W 2D-COSY NMR experiments. We demonstrate herewith a new way for the unambiguous assignment of 183W NMR spectra of polyoxotungstates without any symmetry elements or tungsten atoms in special positions. This way relies on the correlation of the magnitude of 2JW-W coupling constants with the geometry of oxo-bridges in polyoxotungstates. These results open the way to monitor interaction sites of chiral polyoxotungstates with organic ligands." @default.
- W2062425107 created "2016-06-24" @default.
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- W2062425107 date "2006-04-07" @default.
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- W2062425107 title "A Strategy for the Analysis of Chiral Polyoxotungstates by Multinuclear (<sup>31</sup>P, <sup>183</sup>W) NMR Spectroscopy Applied to the Assignment of the <sup>183</sup>W NMR Spectra of α<sub>1</sub>-[P<sub>2</sub>W<sub>17</sub>O<sub>61</sub>]<sup>10</sup><sup>-</sup> and α<sub>1</sub>-[YbP<sub>2</sub>W<sub>17</sub>O<sub>61</sub>]<sup>7</sup><sup>-</sup>" @default.
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- W2062425107 doi "https://doi.org/10.1021/ja0575934" @default.
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