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• W2062433679 endingPage "6745" @default.
• W2062433679 startingPage "6733" @default.
• W2062433679 abstract "Ferrocenecarboxaldehyde is readily transformed into the acetal of (S)-1,2,4-butanetriol (1,3-dioxane structure) and further methylated to give acetal 15. This can then be ortho-lithiated using t-BuLi with very high diastereoselectivity (98% de). Electrophilic quenching provided a large array of compounds of established stereochemistry. Controlled hydrolysis leads to many ortho-substituted ferrocenecarboxaldehydes (98% ee) which themselves are starting materials in the synthesis of various classes of enantiopure ferrocene derivatives with planar chirality of predictable absolute configuration." @default.
• W2062433679 created "2016-06-24" @default.
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• W2062433679 date "1997-10-01" @default.
• W2062433679 modified "2023-10-16" @default.
• W2062433679 title "<b>An Efficient Asymmetric Synthesis of 2-Substituted Ferrocenecarboxaldehydes</b>" @default.
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• W2062433679 doi "https://doi.org/10.1021/jo970075u" @default.
• W2062433679 hasPublicationYear "1997" @default.
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