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- W2062434398 abstract "A binuclear complex with fixed molecular nitrogen [(THF)1.5MgCl3Fe]2N2 (III) and the complexes [(THF)FeCl4]2Mg(THF)2 (II), [C4H5FeCl5Mg(THF)26H20] (IV) and [(C4H5)2FeCl7Mg2(THF)46H2O] (V) have been isolated from the system: FeCl3+ THF + N2 + Mg. Reaction of the nitrogen complex (II) with hydrochloric acid leads to the reduction of the nitrogen to hydrazine. In addition, the introduction of anhydrous ferric chloride into the system causes dehydration of the tetrahydrofuran. As a result of this decomposition an unsaturated hydrocarbon is formed which undergoes σ-bonding with the iron atom of the complex or, alternatively, in the presence of metallic magnesium forms the corresponding Grignard compound." @default.
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- W2062434398 date "1972-12-01" @default.
- W2062434398 modified "2023-10-18" @default.
- W2062434398 title "Reaction mechanism and properties of the compounds formed in the system: FeCl3 + Mg + THF + N2" @default.
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- W2062434398 doi "https://doi.org/10.1016/s0022-328x(00)88337-0" @default.
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