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- W2062471606 abstract "The monomer vinylbis(1-ethoxyethyl)hydroquinone, [vinylhydroquinonebis(ethyl acetal)], was prepared by reacting bromohydroquinone with vinyl ethyl ether, α-chloroethyl ethyl ether being used as catalyst with great care to exclude moisture. The resulting bromohydroquinonebis(ethyl acetal) was subjected to lithium–bromine exchange followed by reaction with ethylene oxide. The resulting β-hydroxyethylhydroquinone bis(ethyl acetal) was dehydrated to the desired monomer over potassium hydroxide at 235°. The overall yield from bromohydroquinone to purified monomer averaged 42%. The monomer polymerized under radical or anionic initiation. Polymer produced under radical initiation showed (in most instances) an intrinsic viscosity in benzene of the order of 0.32 at 29.7°C. The polymer is readily cleaved by dilute methanolic hydrochloric acid to give a polyvinylhydroquinone. A polyvinylhydroquinone prepared under anionic initiation showed an intrinsic viscosity of 0.34 in 90% methanol at 29.7°C. The polymer showed redox properties." @default.
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- W2062471606 date "1964-05-01" @default.
- W2062471606 modified "2023-10-09" @default.
- W2062471606 title "Electron exchange polymers. XX. Preparation and polymerization of vinylbis(1-ethoxyethyl)-hydroquinone" @default.
- W2062471606 doi "https://doi.org/10.1002/pol.1964.100020528" @default.
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