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• W2062505467 abstract "The crystal structure of two iron complexes of 2,9-bis(2-hydroxyphenyl)-1,10-phenanthroline (H2dophen) [Fe(dophen)Cl]2·2HCON(CH3)2 [1·2HCON(CH3)2] and [Fe(dophen)(N-MeIm)2]ClO4 [2] (N-MeIm = 1-methylimidazole) have been determined: 1·2HCON(CH3)2, monoclinic, space group P21/n, a = 11.141(4), b = 15.519(4), c = 13.387(3) Å, β = 93.76(2)°, Z = 4; 2, triclinic, space group P, a = 10.293(1), b = 12.395(3), c = 12.400(6) Å, α = 105.04(4), β = 90.54(4), γ = 99.93(1)°, Z = 2. The cyclic voltammograms of 1 and 2 in dimethylformamide show that the iron complexes undergo three successive reversible reductions with E1/2 = −0.80 V, −2.02 V, −2.45 V for 1 and −0.75 V, −2.03 V and −2.45 V for 2vs. the ferrocenium/ferrocene couple (Cp2Fe+/0) respectively. The first two couples are assigned as the Fe(III)/Fe(II) and Fe(II)/Fe(I) couples, whereas the couple at −2.45 V is assigned to the reduction of the dophen ligand. The Fe(I) species are active towards CO2 reduction. Electrolysis of CO2 in the presence of 1 or 2 at −2.0 V vs. Cp2Fe+/0 gave a mixture of carbon monoxide, formate and oxalate, with formate being the major product. The rate of CO2 reduction was enhanced by the addition of 1,1,1-trifluoroethanol or methanol as the proton source to the electrolyte. Iron carbonyl and iron formato species were detected as intermediates by in-situ FTIR spectroelectrochemistry." @default.
• W2062505467 created "2016-06-24" @default.
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• W2062505467 date "2002-01-01" @default.
• W2062505467 modified "2023-10-07" @default.
• W2062505467 title "Iron(i) complexes of 2,9-bis(2-hydroxyphenyl)-1,10-phenanthroline (H2dophen) as electrocatalysts for carbon dioxide reduction. X-Ray crystal structures of [Fe(dophen)Cl]2·2HCON(CH3)2 and [Fe(dophen)(N-MeIm)2]ClO4 (N-MeIm = 1-methylimidazole)" @default.
• W2062505467 cites W1966729480 @default.
• W2062505467 cites W1968528257 @default.
• W2062505467 cites W1970655201 @default.
• W2062505467 cites W1972308517 @default.
• W2062505467 cites W1975232193 @default.
• W2062505467 cites W1980216192 @default.
• W2062505467 cites W1985235311 @default.
• W2062505467 cites W1986140359 @default.
• W2062505467 cites W1990562968 @default.
• W2062505467 cites W1991470376 @default.
• W2062505467 cites W1991730965 @default.
• W2062505467 cites W1994092010 @default.
• W2062505467 cites W2001766927 @default.
• W2062505467 cites W2005320801 @default.
• W2062505467 cites W2005975026 @default.
• W2062505467 cites W2009913847 @default.
• W2062505467 cites W2010252868 @default.
• W2062505467 cites W2011341872 @default.
• W2062505467 cites W2012782670 @default.
• W2062505467 cites W2013116501 @default.
• W2062505467 cites W2015642243 @default.
• W2062505467 cites W2016901007 @default.
• W2062505467 cites W2020057342 @default.
• W2062505467 cites W2021499053 @default.
• W2062505467 cites W2022274057 @default.
• W2062505467 cites W2022796658 @default.
• W2062505467 cites W2023694897 @default.
• W2062505467 cites W2024750866 @default.
• W2062505467 cites W2025983387 @default.
• W2062505467 cites W2026280071 @default.
• W2062505467 cites W2026625489 @default.
• W2062505467 cites W2030790616 @default.
• W2062505467 cites W2034553016 @default.
• W2062505467 cites W2034693145 @default.
• W2062505467 cites W2035587516 @default.
• W2062505467 cites W2035745300 @default.
• W2062505467 cites W2038623889 @default.
• W2062505467 cites W2038821228 @default.
• W2062505467 cites W2045287476 @default.
• W2062505467 cites W2045845912 @default.
• W2062505467 cites W2046217205 @default.
• W2062505467 cites W2046896984 @default.
• W2062505467 cites W2050615849 @default.
• W2062505467 cites W2058656982 @default.
• W2062505467 cites W2061674669 @default.
• W2062505467 cites W2061694766 @default.
• W2062505467 cites W2062011962 @default.
• W2062505467 cites W2066728845 @default.
• W2062505467 cites W2069807859 @default.
• W2062505467 cites W2074292354 @default.
• W2062505467 cites W2077991980 @default.
• W2062505467 cites W2082619772 @default.
• W2062505467 cites W2082864242 @default.
• W2062505467 cites W2083638309 @default.
• W2062505467 cites W2084791441 @default.
• W2062505467 cites W2084994530 @default.
• W2062505467 cites W2085485409 @default.
• W2062505467 cites W2087490561 @default.
• W2062505467 cites W2089044523 @default.
• W2062505467 cites W2092861679 @default.
• W2062505467 cites W2092973850 @default.
• W2062505467 cites W2095821387 @default.
• W2062505467 cites W2105565769 @default.
• W2062505467 cites W2113738037 @default.
• W2062505467 cites W2122727898 @default.
• W2062505467 cites W2138564710 @default.
• W2062505467 cites W2157834522 @default.
• W2062505467 cites W2172288898 @default.
• W2062505467 cites W227035001 @default.
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• W2062505467 doi "https://doi.org/10.1039/b108472k" @default.
• W2062505467 hasPublicationYear "2002" @default.
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