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• W2062537685 endingPage "4169" @default.
• W2062537685 startingPage "4159" @default.
• W2062537685 abstract "Direct cyclopalladation of (S)-4-tert-butyl-2-methyl-2-oxazoline at the nonactivated tert-butyl group using palladium(II) acetate in acetic acid afforded the first example of an oxazoline-derived exo-palladacycle with an (sp3)C−Pd bond. The structure of the new palladacycle was established using spectroscopic and X-ray studies of the μ-chloro-dimeric complex 2 and two mononuclear triphenylphosphane derivatives: neutral adduct 4 and its cationic benzonitrile-phosphane analogue 5. Analysis of NMR data for compounds 4 and 5 suggests a highly puckered λ(S) conformation of the palladacycle in solution. The X-ray crystal structure of cationic complex 5 confirmed the same highly puckered λ(S) conformation of the palladacycle in the solid state; in addition, it revealed unusual π−π-interactions between the phenyl rings of the benzonitrile and PPh3 ligands and a distorted M-propeller configuration of the PPh3 fragment." @default.
• W2062537685 created "2016-06-24" @default.
• W2062537685 creator A5039188143 @default.
• W2062537685 creator A5062653946 @default.
• W2062537685 creator A5080753130 @default.
• W2062537685 date "2005-07-16" @default.
• W2062537685 modified "2023-09-23" @default.
• W2062537685 title "Cyclopalladation of (<i>S</i>)-4-<i>tert</i>-Butyl-2-methyl-2-oxazoline: An Unprecedented Case of (sp³)C−H Bond Activation Resulting in <i>e</i><i>xo</i>-Palladacycle Formation" @default.
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