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- W2062577978 abstract "Order−disorder transition, microdomain structure, and phase behavior in binary mixtures of low molecular weight polystyrene-block-polyisoprene (SI diblock) copolymers were investigated. For the study, four SI diblock copolymers were synthesized, namely (i) SI-Q having a weight-average molecular weight (Mw) of 2.8 × 104 and polystyrene volume fraction (f) of 0.186, (ii) SI-R having Mw = 1.5 × 104 and f = 0.508, (iii) SI-S having Mw = 1.76 × 104 and f = 0.372, and (iv) SI-M having Mw = 1.55 × 104 and f = 0.626. Then binary mixtures of SI-Q and SI-R and binary mixtures of SI-M and SI-S, with various compositions, were prepared via solvent casting. The order−disorder transition of the binary mixtures was investigated using rheology and small-angle X-ray scattering (SAXS), respectively. Also investigated was the microdomain structure of the binary mixtures using SAXS and transmission electron microscopy (TEM). Experimentally determined phase diagrams are compared with predictions based on a self-consistent mean-field theory." @default.
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- W2062577978 date "1997-09-01" @default.
- W2062577978 modified "2023-09-25" @default.
- W2062577978 title "Order−Disorder Transition, Microdomain Structure, and Phase Behavior in Binary Mixtures of Low Molecular Weight Polystyrene-<i>block</i>-polyisoprene Copolymers" @default.
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- W2062577978 doi "https://doi.org/10.1021/ma970050x" @default.
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