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• W2062584549 abstract "trans-Cyclooctene forms stable π-olefin complexes with aurous chloride and trifluoromethanesulfonate (triflate). The latter can be isolated as the tris trans-cyclooctene complex which shows no tendency for disproportionation of gold(I) to gold(III). It is compared to analogous cationic complexes from copper (I) and silver(I) triflates. Oxidative addition and electron transfer reactions of olefin—gold(I) complexes to afford gold(III) and gold(II) species, respectively, are examined. Attempts to prepare the simple and the coordinatively unsaturated phosphine complexes of gold(I) triflate are also described." @default.
• W2062584549 created "2016-06-24" @default.
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• W2062584549 date "1977-07-01" @default.
• W2062584549 modified "2023-10-01" @default.
• W2062584549 title "Studies of cationic gold(I) complexes: Preparation of tris(trans-cyclooctene)gold trifluoromethanesulfonate" @default.
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• W2062584549 doi "https://doi.org/10.1016/s0022-328x(00)91691-7" @default.
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