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- W2062616454 abstract "First results of the study of monomolecular layers at low pressure of some isomeric glyoximes and their Ni complexes are reported. In the experimental conditions, by extrapolating the curves ( c/p, c ) at zero concentration, it has been possible to get values of the molecular weights in good agreement with theoretical values, independently from molecular associations, which are possible also in non polar solvents. The angular coefficients of the straight lines ( c/p, c ) are characteristic of the glyoximes and of single Ni complexes and allow the differentiation of the isomers. It has not been possible to calculate the ⪡ molecular surface ⪢ because the angular coefficients are positive; and this has been assumed as an indication of molecular attractions, with following associations. This fact is evidenced by normal cryoscopic measurements. We are now studying the behaviour of monomolecular layers at higher pressures, in order to state the values of the ⪡ cosurfaces ⪢ and to draw further informations on the structure of these compounds." @default.
- W2062616454 created "2016-06-24" @default.
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- W2062616454 date "1958-01-01" @default.
- W2062616454 modified "2023-10-14" @default.
- W2062616454 title "Study of some isomeric glyoximes and their Ni complexes by means of monomolecular layers" @default.
- W2062616454 cites W2013548483 @default.
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- W2062616454 doi "https://doi.org/10.1016/0022-1902(58)80221-3" @default.
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