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- W2062643498 abstract "Gel electrolytes were prepared by swelling a self-assembling ABA triblock copolymer with different amounts of a solution of 1 M lithium bis(trifluoromethylsulfonyl)imide salt in γ-butyrolactone. The triblock copolymer had endblocks of polyethylene (PE) and midblocks of poly(ethylene oxide-co-propylene oxide) (PEOPO), where the former blocks constituted 10 wt% of the copolymer. Thus, the electrolyte solution was contained in physical networks consisting of PEOPO chains interconnected by crystalline PE phase domains. The gels showed a stepwise increase in the ionic conductivity as a consequence of the melting of the PE domains at approximately 100 °C. Also, the conductivity at room temperature increased significantly after annealing above this temperature. Block copolymer gels containing 70 wt% of electrolyte solution reached conductivities of 1 mS/cm at 20 °C." @default.
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- W2062643498 date "2002-11-01" @default.
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- W2062643498 title "Physically crosslinked gel electrolytes based on a self-assembling ABA triblock copolymer" @default.
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- W2062643498 doi "https://doi.org/10.1016/s0032-3861(02)00585-2" @default.
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