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- W2062688324 abstract "Abstract Polycyanoacetylene was prepared by dehydrochlorination of poly-α-chloroacrylonitrile at low temperature. Thin films were simply obtained by spreading a DMF solution onto a stainless steel substrate. Transmission electron microscopy revealed a highly crystalline structure. Two different morphologies were observed : large isolated single crystals and numerous small crystals dispersed in the precursor matrix. The electrochemical behaviour of polycyanoacetylene was studied using a (-CH=C(CN)-) /(PEO)8LICIO4/Li cell. Cyclic voltammetry indicated a very reversible behaviour. Lithium intercalation/deintercalation occurred at ca 2.6 V vs Li/Li+. This high value compared to polyacetylene may be attributed to the electron withdrawing effect of the cyano- group. These properties make polycyanoacetylene suitable for use as a positive electrode in batteries." @default.
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- W2062688324 date "1985-03-01" @default.
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- W2062688324 title "Electrochemical Doping of Polycyanoacetylene, A New Conducting Polymer" @default.
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- W2062688324 doi "https://doi.org/10.1080/00268948508074885" @default.
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