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• W2062708064 abstract "Lithium-metal oxides with a high formal Li2O content, such as Li5FeO4 (5Li2O•Fe2O3) and a Li2MnO3•LiFeO2 composite ({Li2O•MnO2}•{Li2O•Fe2O3}) have been explored as electrocatalysts for primary and rechargeable Li-O2 cells. Activation occurs predominantly by Li2O removal, either electrochemically or chemically by acid-treatment. Superior electrochemical behavior is obtained if activation occurs by acid-treatment; Li2MnO3•LiFeO2 catalysts provide 2516 mAh/g (carbon) corresponding to 931 mAh/g (electrocatalyst + carbon) during the initial discharge. The reaction is reasonably reversible during the early cycles. The approach has implications for designing electrocatalysts that participate through electrochemical Li2O extraction/reformation reactions, offering exceptionally high capacities." @default.
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• W2062708064 date "2011-01-01" @default.
• W2062708064 modified "2023-10-01" @default.
• W2062708064 title "Activated Lithium-Metal-Oxides as Catalytic Electrodes for Li–O2 Cells" @default.
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• W2062708064 doi "https://doi.org/10.1149/1.3555366" @default.
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